Electronic Resource
Hoboken, NJ
:
Wiley-Blackwell
Journal of Polymer Science
3 (1948), S. 438-443
ISSN:
0022-3832
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The adiabatic technique of making kinetic measurements has been applied to published time--temperature data concerning the vulcanization of Buna S with 6% sulfur. The kinetic parameters of the rate-determining step are calculated within stated limits of accuracy; the rate-determining step is thereby identified as the reaction S8 (ring) → S8 (chain biradical) which has been speculatively advanced as the first step in vulcanization by some investigators.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1948.120030318
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