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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 1 (1946), S. 529-534 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An elementary theory is given for the rolling of polymeric materials, for the case in which the deformation is largely an irreversible flow of the viscous type. The theory treats the rolling process as the homogeneous deformation of volume elements over the arc of contact and neglects frictional forces that may exist at the roll surface. A numerical example is given of the calculation of roll pressure, which agrees with available data to a factor of two or better. A more complete test will require parallel measurements of viscosity and roll pressure on the same material.
    Additional Material: 3 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 2 (1947), S. 449-449 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Methods for the preparation of fiber-forming polymeric amides from ω-amino acids and The variation in melting points of the polymeric their amide-forming derivatives are described. The variation in melting points of the polymeric amides with increasing chain length of the recurring unit is discussed.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 11 (1953), S. 225-231 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: For a particular sample of polystyrene, different osmometric estimates of Mn have been reported. The possibility that the difference is due, in the one case, to permeation of the membrane by low molecular weight polymer has been carefully considered. It is shown that this can not be the explanation. The difference is in some way associated with chemical differences in the membranes used. Apart from these considerations of error, the significance of the number-average molecular weights of the unfractionated polymers of commerce is shown to be more acutely dependent upon the detail of the low molecular weight end of the distribution than may be realized. The present calculations are based upon a realistic estimate of the low molecular weight polymer content of commercial polymers.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 1 (1946), S. 535-539 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In the rolling of Plastic sheet the viscous work gives rise to heating of the plastic sheet. The maximum temperature reached in the interior of the sheet during shearing is of the interest, both in the theoretical calculation of roll pressure, and from the point of view of possible thermal decomposition effects. A calculation is given for a simple, some-what artificial, model, which leads to an upper value for this maximum temperature if a measurement of the average temperature of the emergent sheet is given. The model taken is that of an infinite sheet, of thickness 2δ, in which heat is continuously liberated at the rate of 4ηφ2 cal. cc. -1 sec. -1, where φ is the relevant value of the rate of compression (assumed constant across the sheet). The curve giving the temperature distribution across the sheet is calculated numerically for two cases; it is relatively flat, as would be expected on physical grounds, since the viscosity, η, decreases as the temperature rises. It is concluded that these thermal effects may be neglected in the calculation of roll pressure in Part 1.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 2 (1947), S. 306-313 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Methods for the preparation of fiber-forming polymeric amides from polymethylene diamines and polymethylene dicarboxylic acids, and the stabilization of these polymers against viscosity changes, have been described. The variation in physical properties, particularly melting points, of the polymeric amides with increasing chain length of the components has been discussed.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 2 (1947), S. 352-352 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 3 (1948), S. 345-349 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The surface tension of polyoxyethylene glycol in water leads to a value for the area per molecule which shows that the polymer molecules lie approximately flat in the surface. Molecular weight determinations by end-group analysis and freezing-point depression are compared with values of the intrinsic viscosity and limiting area per molecule.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 25 (1953), S. 672-676 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Während die Vorgänge bei der Verdampfung unter Atmosphärendruck vor allem durch Jacob und Mitarbeite weitgehend geklärt sind, besteht über die Verdampfung im Hochvakuum noch keine einheitliche Vorstellung. In jüngerer Zeit veröffentlichte Untersuchungen von K. C. D. Hickman und D. J. Trevoy1 geben einen Einblick in die Hochvakuum-Verdampfung und Molekular-Destillation, über welche nachfolgend berichtet wird.
    Additional Material: 11 Ill.
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  • 10
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A micromethod is described for density determinations of artificial cellulose fibers by the floating method, in carbon tetrachloride in a dry and air-free atmosphere, permitting an accuracy of one part per thousand. The density is derived from the temperature at which the samples neither sink nor float. This temperature varies, with the kind of fiber, between 45° and 65°C. Measurements of the refractive power were carried out simultaneously. The refractivity calculated according to Gladstone and Dale yields slightly lower figures than those found for model fibers in the preceding communication (Part II). The average difference amounts to seven parts per thousand and is ascribed to a systematic error in the density determinations, due to a slight absorption of carbon tetrachloride by the fibers at elevated temperatures. This explanation is supported by experiments. The density of native ramie, of contracted and reoriented ramie, and of several series of rayon fibers spun with increasing stretch, is given. The conclusion is reached that the density is a measure of the percentage of crystalline substances in the fiber and it is shown that there is a correlation between density and sorptive capacity toward water vapor. The percentage of crystalline matter is estimated to be 55-60% in native ramie and 20-25% in rayon.
    Additional Material: 2 Ill.
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