ISSN:
0022-3832
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The infrared spectra of synthetic poly-1-phenyl- and poly-2-phenylbutadienes have been examined, principally in the region from 9 to 15 μ. The different intramolecular structures of these polymers, corresponding to the different types of monomer additions (1,4, 1,2, and 3,4) were examined by this method; the data are in complete agreement with the chemical results as reported previously. The influence of the method of polymerization on the internal structures of the polymers is taken in evidence; the presence of the aromatic substituent in position 1 or 2 in the monomer molecule exerts a large influence on the position and the intensity of the characteristic absorption bands, if they are compared with the results for synthetic polyisoprenes.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1954.120137107
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