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  • 1950-1954  (2)
Collection
Publisher
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 5 (1950), S. 253-258 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Die Mischpolymerisation von Maleinsaeure Anydrid mit verschiedenen Vinyl-Verbindungen wie Methakrylsaeure, Methylester, Vinylchlorid, Vinylazetat und Isopropenylazetat wurde untersucht. Die Verhaeltnisse der Geschwindigkeits-Konstanten r1 und r2 wurden fuer jeden dieser Faelle festgestellt. Die Mischpolymerisation mit Monomeren, die eine elektronreiche Doppelverbindung enthalten, zeichnet sich durch eine hohe Selektivitaet aus. In diesen Faellen koennen die Ergebnisse nicht gaenzlich durch das Alfrey-Price Schema erklaert werden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 13 (1954), S. 477-485 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The infrared spectra of synthetic poly-1-phenyl- and poly-2-phenylbutadienes have been examined, principally in the region from 9 to 15 μ. The different intramolecular structures of these polymers, corresponding to the different types of monomer additions (1,4, 1,2, and 3,4) were examined by this method; the data are in complete agreement with the chemical results as reported previously. The influence of the method of polymerization on the internal structures of the polymers is taken in evidence; the presence of the aromatic substituent in position 1 or 2 in the monomer molecule exerts a large influence on the position and the intensity of the characteristic absorption bands, if they are compared with the results for synthetic polyisoprenes.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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