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  • 1950-1954  (6)
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  • 1950-1954  (6)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 133 (1953), S. 32-34 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Es wurde die Wirkung der Löslichkeit von Silberchromat bei der Bildung von Liesegang-Ringen untersucht, da dieses weitgehend unlösliche Salz eine starke Variation seiner Löslichkeit bei Änderung der Wasserstoffionenkonzentration zeigt. Liesegang-Ringe besitzen größere Abstände bei gesteigerter Löslichkeit des Silberchromats durch höhere Azidität des Mediums. Die Ringe werden schärfer, wenn verdünnte Chromatlösungen oder Nitratlösungen verwendet werden. Es müssen beträchtliche Unterschiede in der Konzentration der zwei reagierenden Lösungen bestehen, wobei die von außen diffundierende immer die konzentriertere sein muß. Die günstigsten Konzentrationsverhältnisse wurden bestimmt.
    Notes: Abstracts The effect of the solubility of insoluble silver chromates in the formation of Liesegang rings has been studied as this insoluble salt shows a marked yariation in its solubility with the change in hydrogen ion concentration. The Liesegang rings are less closely packed as the solubility of silver chromate is increased with the increasing acidity of the medium. Rings become more distinct as the chromate solutions used are diluted or the concentrated solution of silver nitrate diffusing from the top is diluted. There should be considerable difference in the concentrations of the two interacting solutions, the one diffusing from the top being always concentrated. Concentrations of the interacting solutions, suited for well defined rings in the gelatin medium, have been determined.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 133 (1953), S. 34-37 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Das kolloide Verhalten von Silberchromat bei Erzeugung periodischer Fällungen besonders in Agar-Agar wurde untersucht. Silberchromat bildet keine stabile kolloide Lösung im Agar-Agar-Sol, doch wurde festgestellt, daß eine kolloide Lösung in Gegenwart von Natriumzitrat-, Binatriumhydrophosphat-, Aluminiumnitrat- und Thoriumnitrat-Lösungen erhalten werden kann. Daher können Liesegang-Ringe bei Gegenwart dieser Salze auch in Agar-Agar-Gelen entstehen. Liesegang- Ringe von Silberchromat in Agar-Agar-Gelen lassen sich auch in Gegenwart von Wasserstoffionen erzeugen, so, wenn statt des Chromates oder der Bichromatlösung Chromsäure verwendet wird. Es sind also bei Bildung von Liese gang-Ringen aus Silberchromat die Bildung eines leicht durch diffundierende Ionen koagulierbaren Kolloids oder steigende Löslichkeit die wichtigen Faktoren.
    Notes: Abstracts The colloidal behaviour of silver chromate in producing periodic precipitation, specially in agar agar medium, has been studied. Silver chromate does not form any stable colloidal solution in agar agar sol but it has been observed by us that its colloidal solution may be obtained in the presence of sodium citrate, disodium hydrogen phosphate, aluminium nitrate and thorium nitrate solutions. Further, Liesegang rings of silver chromate in agar agar gel are formed in the presence of these salts. Liesegang rings of silver chromate are also observed in the agar agar medium in presence of hydrogen ions, when chromic acid is taken in the gel in place of a chromate or dichromate solution. Thus in the formation of Liesegang rings of silver chromate, the formation of a colloid easily coagulable by the diffusing ions or an increased solubility are the important factors.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 257-259 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Zusammensetzung des Niederschlages, der bei Zusatz von Silbernitrat- zu einer Chromatlösung ausfällt, hängt vom PH der Chromatlösung und von den Konzentrationen der Ausgangslösugen ab. Obwohl sie sich unter bestimmten Bedingungen der Formel Ag2Cr2O7 nähert, kann diese Verbindung aus wäßriger Lösung nicht rein dargestellt werden.
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  • 4
    Publication Date: 1953-10-01
    Print ISSN: 0372-820X
    Electronic ISSN: 1435-1536
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Springer
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  • 5
    Publication Date: 1953-10-01
    Print ISSN: 0372-820X
    Electronic ISSN: 1435-1536
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Springer
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  • 6
    Publication Date: 1954-03-01
    Print ISSN: 0044-2313
    Electronic ISSN: 1521-3749
    Topics: Chemistry and Pharmacology
    Published by Wiley
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