ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The isomer ratio in the mono-nitration of toluene and α-d3-toluene has been measured by gas chromatographic separation. The percentage of o- and p-nitrotoluene is not influenced significantly by the isotopic substitution in the methyl group; there is, however, a difference in the formation of the m-isomer, demonstrating an inverse secondary isotope effect (kH/kD = 0.94) for the substitution in m-position.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19610440418
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