ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
With a rapid flow apparatus the investigation of the simple protonation of WO42- was achieved (pK1 + pK2 = 8,1, both H+ being added almost simultaneously). The rapid condensation which follows the protonation leeds during the first decisecond to a product of Z = 1.25, probably H5W4O163-. A few minutes later, a new preequilibrium is established with (according to Sasaki) HW6O215- (Z = 1.167) as practically the only polynuclear product present. The final equilibrium is reached only very slowly.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19620450729
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