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  • 1960-1964  (1)
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    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 333 (1964), S. 171-180 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The vibration-spectra of the compounds P(CH3)nCl5-n prove the existence of phosphonium salts [P(CH3)nCl4-n]+Cl-. The spectra are very similar to those of the isoelectronic Methylchloro-silanes. In the ion [P(CH3)3F]+Cl- the PF force constant is surprisingly low.
    Notes: Aus den Schwingungsspektren der Verbindungen P(CH3)nCl5-n ergibt sich, daß sie als Phosphoniumsalze [P(CH3)nCl4-n]+Cl- vorliegen. Diese Phosphoniumionen gleichen schwingungsspektroskopisch weitgehend den isoelektronischen Methylchlorsilanen. Die Verbindung P(CH3)3FCl liegt als [P(CH3)3F]+Cl- vor, jedoch mit stark gelockerter PF-Bindung.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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