ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Polymer and Materials Science  (409)
  • 1960-1964  (409)
Collection
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 1991-2002 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Infrared spectra indicate that carboxyl-substituted acrylic copolymers react appreci8bly with a butylated melamine-formaldehyde resin when heated at 120°C. for 30 min., but under these conditions acid catalysis is needed before epoxy- or amido-substituted copolymers will crosslink with the melamine-formaldehyde resin. Two methods have been used to synthesize hydroxyl-substituted acrylic copolymers. First, a glycidyl methacrylate copolymer was reacted with diethplamine. Second, an acrylic acid copolymer was heated under reflux with butylene oxide in the presence of a basic catalyst. This second method was used to esterify a vinyl toluene-acrylic acid-acrylamide copolymer which was subsequently treated with paraformaldehyde. The resulting hydroxy-methylolamido copolymer intercondensed when heated at 120°C. for 30 min., somewhat as did the hydroxy copolymer with melamine-formaldehyde resin blends.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 5 (1961), S. 527-533 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A system is described for automatic collection of stress-strain data for polymeric films on magnetic tape for subsequent automatic data reduction and computation of a variety of stress-strain parameters. Two shaft analog-to-digital encoders attached to a conventional tensile tester feed digital information to an incremental pulse recorder which stores all stress and strain data in two channels on 0.625-in. magnetic tape. Specimen information and test constants are inserted by the operator through a keyboard located at the tensile tester. The tape is subsequently fed into a standard digital computer through a special incremental pulse magnetic tape reader. The data pulses are internally stored and converted by means of a special program into eight significant stress-strain parameters for polymeric film samples, plus averages and standard deviations for groups of replicate determinations. These parameters include: corrected length of specimen, initial maximum tensile modulus, offset yield stress, strain at break, strain at maximum stress, maximum tensile stress, tensile stress at break, and work to break. While the program described applies to polymer film testing, both it and the digital recording equipment accessories are applicable with suitable modification, to any analog experimental data. Significant savings in man-hours and increased information output result from use of this system.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S46 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The free-radical polymerization of vinyl fluoride has been studied with the use of organic peroxide and azo initiators over the temperature range of 60-150°C. and at pressures of 75-1000 atm. Molecular weights of the polymers by osmotic pressure or radiotracer techniques were found to vary over the range of 45,000 to 180,000 depending on polymerization conditions employed. Stabilized high molecular weight polyvinyl fluoride may be compression-molded into tough, high-impact strength bars, or the unstabilized material may be cast into films from solvents such as dimethylformamide. The films, which may be cold drawn, are tough, brilliantly clear, and have tensile strengths near 8000 lb./in.2 They are also extremely resistant to weathering, maintaining clarity and cold drawability even after ten years' exposure in Florida.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 1919-1919 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Investigations of the viscoelastic aspects of the mechanical behavior of polymers have been limited almost exclusively to relatively simple conditions of homogeneous stress, that is, to tension or shear loadings. In the present work a study has been made from the viscoelastic standpoint of the response of several elastomers to a much more complex type of stress distribution arising from penetration up to failure by a cylindrical indentor for a range of temperatures and rates of penetration. The failure or “puncture point” was determined by a dip in the recorded curve of load versus depth of penetration. The puncture strength values were reduced to 25°C. by applying the ratio of absolute temperatures and plotted against the logarithm of the reciprocal of the rate of penetration. These curves were then shifted on the time scale to give a master curve after the manner of Tobolsky and of Ferry. The logarithms of the shift factors thus obtained were related to the reciprocal of the absolute temperature over the range studied. The results indicate a broader generality for the viscoelastic principle of time-temperature equivalence than has usually been supposed.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 461-468 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The changes in solvent resistance and solution viscosity of polyethylene glycol and polypropylene glycol after heating with dicumyl peroxide at 140°C. are consistent with crosslinking of the former and degradation of the latter. Analytical work showed that in both cases all of the peroxide decomposed could be accounted for acetophenone and cumyl alcohol. In the case of polyethylene glycol, crosslinking results from abstraction of secondary hydrogen atoms and dimerization of the resulting radicals; in the case of polypropylene glycol abstraction of tertiary hydrogen atoms leads to radicals which break down by scission at a C—O bond to give a ketone and a more stable radical. This latter process proceeds with an efficiency of unity.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 49 (1961), S. 533-541 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The preparation of a completely isopropylated polystyrene by polymerization of p-isopropylstyrene monomer is described. This polymer was autoxidized in cyclohexane with lauroyl peroxide to give a material of good reproducibility and high purity. Methyl methacrylate was successfully grafted to the polymeric hydroperoxide by using a sugar-containing recipe. Homopolymer was separated from the graft copolymer by extraction. Evidence for grafting was obtained from solubility and fractionation behavior, as well as from light-scattering and viscosity measurements.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 51 (1961), S. 527-539 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Through x-ray and infrared examinations of stereoregular polymers and copolymers of vinylaromatic monomers, the occurrence of chain isomorphism phenomena, together with many cases of a new type of isomorphism between monomeric units, have been proved. Isomorphism of macromolecules, allowing true solid solutions, has been observed when melting and crystallizing mixtures of homopolymers (i.e., isotactic polystyrene) and of crystalline copolymers (i.e., styrene-p-methylstyrene) having the same identity period and differing very little in lattice constants. Isomorphism among monomeric units occurs in copolymerizing monomers that have a chemical nature and shape slightly different one from the other, e.g., styrene and o-fluorostyrene. This allows the formation of crystallizable copolymers in the entire composition range. They show physical properties (lattice constants, melting temperatures, etc.) continuously varying between those of the pure homopolymers. The occurrence of isodimorphism phenomena has been observed in crystalline copolymers obtained from monomers the homopolymers of which have different crystalline structures (e.g., styrene-p-fluorostyrene), and also in copolymerizing styrene with monomers (e.g., p-methyl, p-chlorostyrene) giving only amorphous homopolymers. In the latter case, of course, the copolymers show crystallinity only in a limited composition range.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 58 (1962), S. 869-880 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The polymerization of acrylonitrile initiated by diethyl sodiomalonate in dimethylformamide has been investigated. The degree of polymerization was found to be independent of the monomer conversion but was dependent on the extent of polymerization. The polymers produced were examined for functional groups by infrared spectroscopy. An anionic mechanism involving hydride ion transfer to monomer has been suggested. The kinetics of the reaction can be followed because of the slow initiation step and are found to be governed by the rate expression -d[M]/dt = k[M]2[C]. The decrease in DP with increasing conversion is due to degradation of the polyacrylonitrile by basic ions. The ratios of the rate constants for both the monomer and polymer transfer reactions to the rate constant for propagation have been determined. The coloration of the polymers appears independent of the degradation reaction.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...