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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The product prepared following the method of GOEHRING and FELDMANN from H2S2O3 and S2Cl2 is not a „spectrum“ of different salts as stated by WEITZ and BECKER, but really K2S6O6, which is also prepared from H2S2O3 and HNO2. Tetrasulfane-disulfonate does not only exist in the neutral form K2S6O6, but also in a „acid“ form with a part of the potassium - nonstoichiometrically - replaced by H+. The two forms have different shape and X-ray spectra.
    Notes: Bei dem nach GOEHRING und FELDMANN aus H2S2O3 und S2Cl2 dargestellten Produkt handelt es sich nicht, wie von WEITZ und BECKER angegeben, um ein „Spektrum“ verschiedener Salze, sondern um einheitliches K2S6O6, wie es auch aus H2S2O3 und HNO2 erhalten wird. Tetrasulfan-disulfonat existiert neben der neutralen Form K2S6O6 noch in einer „saueren“ Form, bei der ein Teil des Kaliums - nichtstöchiometrisch - durch H+ ersetzt ist. Die beiden Formen unterscheiden sich in Aussehen und Röntgenspektrum voneinander.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 188-194 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The separation of sulfane-disulfonates, sulfite and thiosulfate by anion-exchangers has been studied. Whereas K2S6O6 is decomposed on the column, the salts K2S3O6, K2S4O6 and K2S5O6 may be separated quantitatively.
    Notes: Die Trennung von Sulfan-disulfonaten, Sulfit und Thiosulfat mit Anionenaustauschern wird untersucht. Während K2S6O6 auf der Säule zu rasch zerfällt, lassen sich die Salze K2S3O6, K2S4O6 und K2S5O6 quantitativ voneinander trennen.
    Additional Material: 1 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 130-140 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reaction of hydrogen sulfide with sulfuryl chloride in the ratio 2:1 leads in benzene solution to hydrogen chloride, water, sulfur, and disulfur monoxide, S2O, which is surprisingly stable under the prevailing conditions. The reaction of sulfuryl chloride with liquid hydrogen sulfide leads to the formation of sulfanes and chlorosulfanes, respectively, besides other products, depending on the molar ratio H2S:SO2Cl2.
    Notes: Schwefelwasserstoff reagiert mit Sulfurylchlorid beim molaren Einsatz 2:1 in benzolischer Lösung unter Bildung von Chlorwasserstoff, Wasser, Schwefel und Dischwefelmonoxid S2O, das unter den herrschenden Reaktionsbedingungen überraschend stabil ist. Mit flüssigem Schwefelwasserstoff bildet SO2Cl2 im Unterschuß u. a. Sulfane, im Überschuß Chlorsulfane.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 122-129 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reaction S + 2 HJ → H2S + J2 of S8 solutions in CCl4 is very slow, but is accelerated very much in the case of S6 or Sx* (formed by splitting of S8 rings under the influence of light). A simultaneous determination of content and oxidation state of sulfur in mixtures of sulfur compounds with elemental sulfur by the “HJ method” therefore is only possible if the elemental sulfur is present in the S8 form and if the violet and ultraviolet part of the spectrum is excluded during the experiment.
    Notes: In CCl4 gelöster S8-Schwefel reagiert mit HJ nur sehr langsam nach S + 2 HJ → H2S + J2. Diese Reaktion verläuft dagegen mit S6 bzw. mit den durch Lichteinfluß erzeugten Spaltprodukt des S8-Ringes, Sx*, rasch, weshalb die „Jodwasserstoffmethode“ zur Ermittlung des Gehaltes und der Oxydationsstufe von Schwefel in Gemischen des Elementes mit seinen Verbindungen nur dann anwendbar ist, wenn unter Ausschluß des violetten und ultravioletten Anteils des Spektrums gearbeitet wird und der elementare Schwefel in seiner energieärmsten Form, also als S8-Molekel, vorliegt.
    Additional Material: 4 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 79 (1967), S. 99-100 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 76 (1964), S. 615-615 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 6 (1967), S. 955-956 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 327-328 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 660-660 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 661-661 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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