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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 969-979 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The salt rejection properties of cellophanes are substantially increased, and permeation rates decreased, by pretreatment with certain metal ions or presence of these ions at low concentration in feed solutions. In a typical case, a cellophane which initially rejected about 20% of salt from a 0.05M NaCl solution rejected over 70% in Presence of 10-3M ThCl4. Permeation rates were decreased, usually be a factior of 2 or 3. Additives found to have a marked effect were Fe(III), Th(IV), U(VI), Cu(II), and hydrolyzed pb(II). Mg(II), Ba(II), La(III), and unhdrolyzed Pb(II) had little effect. The mechanism by which the additives affect the cellophane is not clear.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 100 (1967), S. 271-279 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der Diphenoxy-phosphoryl-Rest ist eine zur Blockierung der 2-Aminogruppen in Aminozuckern geeignete Schutzgruppe, die die Koenigs-Knorr-Synthese zu 1→3-verknüpften Disacchariden mit zwei Aminozucker-Einheiten ermöglicht. Kondensation von 2-[Diphenoxy-phosphorylamino]-3.4.6-tri-O-acetyl-2-desoxy-α-D-glucopypyranosylbromid (5) mit der an der 3-Hydroxylgruppe unblockierten Verbindung 2 führt bevorzugt zum 1→3-β-verknüpften Disaccharid 8a. Über eine Reihe von Entblockierungsschritten ist daraus 2-Acetamino-3-O-[2-acetamino-2-desoxy-β-D-glucopyranosyl]-2-desoxy-α-D-glucopyranose (12) in kristallisierter Form erhältlich.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 100 (1967), S. 2655-2663 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Reaktion von 2-Diphenoxyphosphorylamino-3.4.6-tri-O-acetyl-2-desoxy-α-D-gluco-pyranosylbromid (9) mit 2-Amino-5.6-O-isopropyliden-2-N.3-O-carbonyl-2-desoxy-D-glucose-diäthylacetal (4) in Benzol bei Gegenwart von Hg(CN)2 führt bevorzugt zum 1→4-α-ver-knüpften Disaccharid 12a. Über eine Reihe von Entblockierungsschritten ist daraus 2-Acetamino-4-O -[2-acetamino-2-desoxy-α-D-glucopyranosyl]-2-desoxy-D-glucose (18) in kristallisierter Form erhältlich.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 2 (1969), S. 1073-1083 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Based on the quasi-equilibrium theory of mass spectra it is shown that the intensity ratio [A]+/[M]+, where [A]+ is a fragment ion and [M]+ is the molecular ion, is given by [A]+/[M]+ = f′ (k1/kt) ((1/f) - 1), where f is the fraction of molecular ions with insufficient energy to fragment, f′ is the fraction of [A]+ ions with insufficient energy to fragment, and k1/kt is the fraction of fragmenting molecular ions which form [A]+. For substituted acetophenones it is shown that f depends on the substituent present and that f′ k1/kt is also substituent dependent for formation of both [CH3CO]+ and [YC6H4CO]+. It is also shown that no direct information concerning the effect of a substituent on the rate of a particular fragmentation reaction can be obtained from intensity studies.The ionization potentials of the parent molecules and the appearance potentials of the [YC6H4CO]+ fragment ions have been measured for fifteen substituted acetophenones and the correlations with substituent constants are discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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