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  • 550 - Earth sciences
  • Chemical Engineering
  • 1965-1969  (165)
  • 1
    Electronic Resource
    Electronic Resource
    The numerical solution of boundary-layer problems (1965)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 733-739 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method for numerical solution of boundary-layer problems has greater applicability as well as greater speed and accuracy than the several previously proposed methods. The method uses the Goertler-transformed equations and a nonlinear finite-difference procedure. In most earlier work on difference methods the equations have been linearized at each step parallel to the boundary. The method of treatment of the boundary conditions on the equation of change for energy or mass transfer is shown to have an important influence on accuracy, and a new, more accurate method of treating boundary conditions involving the normal derivative is presented.Typical complete solutions are compared with the several methods. The solutions include both similar and more general flows up to separation, as well as coupling between the momentum and energy-balance equations.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690110432
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  • 2
    Electronic Resource
    Electronic Resource
    Development of the Scatchard-Hildebrand and Wohl equations in terms of pair and triplet weighting functions (1967)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 311-315 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A previous paper introduced the pair-type-probability (PTP) function for use in molecular corresponding states theory. The present paper develops the predictive equations of Scatchard and Hildebrand and the correlation equations of Wohl from particular pair and triplet weighting functions for clusters of two and three molecules in a liquid mixture. The cluster-weighting idea therefore unifies the major prediction and correlation schemes now in engineering use.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690130221
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  • 3
    Electronic Resource
    Electronic Resource
    Application of molecular corresponding states theory to highly nonideal liquid mixtures (1967)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 303-311 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: There are four points of flexibility in present molecular formulations of the corresponding states idea. At these points the procedure followed or the numerical values can be tailored to achieve better agreement between predicted and experimental properties without violation of physical principles. These flexibilities are the exponent values used in the pair-potential function, the averaging procedure used to obtain an effective mixture pair-potential function, the combination rule for unlike-pair parameters, and the selection of a reference substance. The first two flexibilities are used in this paper to show that the conformal-parameter equations can correlate excess free energy and activity coefficient data of highly nonideal liquid mixtures. A pair-type-probability function is introduced in the averaging procedure used to obtain a mixture pair-potential function. Any macroscopic or molecular property may be used in this weighting function to improve mixture-property prediction.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690130220
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  • 4
    Electronic Resource
    Electronic Resource
    Bounding chemical reactor transients by estimation of growth or decay rates (1968)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 934-939 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: If the transient equations of a plug flow tubular reactor are transformed into a set of corresponding ordinary differential equations, stability information for the former may be obtained graphically from knowledge about the transients of the latter. The analysis presented in this paper combines this simplification with the definitions and theorems of Weiss and Infante to propose a method of direct computation whereby transient bounds may be found for this important class of distributed-parameter chemical reactor systems.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690140620
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  • 5
    Electronic Resource
    Electronic Resource
    Determination of transient plate efficiencies from operational data (1967)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 540-545 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methods are presented for the determination of the transient values of the vaporization efficiencies from the knowledge of various combinations of the transient values of operating variables. For the case where the temperature and the composition of the liquid phase for each plate are known, a direct solution for the vaporization efficiencies is presented. Also, a method is presented for the determination of the mixing parameters of a generalized plate model on the basis of known transient values of certain operating variables.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690130325
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  • 6
    Electronic Resource
    Electronic Resource
    Calorimetric determination of the isothermal effect of pressure on the enthalpy of methane and two methane-propane mixtures (1968)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 923-928 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By using an isothermal throttling calorimeter, built for recirculating vapor operation, the effects of pressure on the enthalpy of methane and two methane-propane (93.9 and 86.2% methane) mixtures were measured. Pure methane was run at 150°F. and the two mixtures were studied at 90, 150, and 200°F. The pressures for these experiments were 500, 1,000, 1,500, and 2,000 lb./sq.in.abs.The resulting data were compared with similar data from other sources for these same systems and conditions. Agreement is good with enthalpy values obtained from both experimental volumetric and Joule-Thomson data.Prediction methods for the isothermal pressure effect on the enthalpy are compared with these data. These methods demonstrate the reliability of the Redlich-Kwong and Benedict-Webb-Rubin equations and Pitzer's corresponding states correlation for calculating isothermal enthalpy changes for these systems and conditions.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690140618
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  • 7
    Electronic Resource
    Electronic Resource
    Vapor-liquid equilibria in mixtures of n-alcohols and their esters (1967)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 814-815 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690130442
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  • 8
    Electronic Resource
    Electronic Resource
    The stability of nonlinear systems in the region of linear dominance (1965)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 474-480 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A technique has been developed for finding quantitative regions of asymptotic stability for nonlinear systems by using a known proof of the theorem which substantiates the linearization. In a sense, the method defines a region in which the first-order approximation is dominant from the point of view of stability. While the computations necessary can be somewhat involved, the procedure is essentially identical in all situations, and once established, can easily be used for a vast class of autonomous systems. The practical problems of both reversible and irreversible chemical reactions occuring in a continuous flow stirred vessel have been analyzed. Stability regions were obtained which are sufficiently extensive to be practical from the process viewpoint.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690110321
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  • 9
    Electronic Resource
    Electronic Resource
    Determination of plate efficiencies from operational data: Part II (1965)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 678-685 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method for the determination of the plate efficiencies for existing conventional and complex columns is presented. Information, such as any combination of product distributions, plate temperatures, and plate compositions, which is in addition to that required to solve a problem for a fixed column is used to determine efficiencies.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690110421
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  • 10
    Electronic Resource
    Electronic Resource
    Identification and adaptation in control loops with time varying gain (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 83-89 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented to apply the gain identification procedures developed in a companion paper to a control system. The method employs a small identification tank which follows the control tank; the identification tank is perturbed to estimate the gain of the process (controlled tank system). The effects of load changes on the identification system are minimized by this approach.The results of analog and digital computer simulations of this adaptive process are given. Both a general system with linear change in gain and a pH control system with a step change in concentration of the buffer species are studied. Process gain changes up to 20:1 are introduced.It is concluded that an adaptive control system of this type can be designed to maintain good control characteristics in a process experiencing wide gain variation. Criteria are presented to aid in the design of an adequate identifier.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120117
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