ISSN:
0570-0833
Keywords:
Hexamethyl(Dewar benzene)
;
Dewar benzene
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hexamethyl(Dewar benzene) was first obtained by bicyclotrimerization of 2-butyne in the presence of aluminum chloride. This preparation provided a basis for a comprehensive study of the chemical reactivity of Dewar benzene derivatives. Interesting information concerning the reactivity of the permethylated Dewar benzene system can be deduced from its behavior on hydrogenation and oxidation, and, in particular, from the addition of H-acidic compounds and from the substitution and elimination reactions of the resulting adducts.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196705181
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