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  • Springer  (63)
  • Würzburg : Freunde der Würzburger Geowissenschaften
  • 1995-1999  (39)
  • 1965-1969  (25)
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  • 1
    Call number: S 93.0569(25)
    In: Beringeria
    Type of Medium: Series available for loan
    Pages: 173 S.
    Series Statement: Beringeria 25
    Classification:
    Regional Geology
    Language: English
    Location: Lower compact magazine
    Branch Library: GFZ Library
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 47 (1999), S. 219-238 
    ISSN: 1573-515X
    Keywords: dissolved humic substances ; FTIR spectroscopy ; land use history ; peat ; synchronous fluorescence spectroscopy ; UV/VIS spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The elemental composition and spectroscopic properties of dissolved fulvic acids isolated from different sampling media (topsoil, ground and surface water) of a natural fen area (high portion of organic soils) were examined to reveal the effects of land use history. These effects need to be known if dissolved humic substances are to be a major factor in identifying the impact of present and future changes in land use. Dissolved fulvic acids (topsoil, groundwater) from highly degraded peatlands (due to a long-term agricultural use) exhibit lower C/N ratios, higher absorption in the UV spectra, and higher absorption at 1,620 cm−1 in the FTIR spectra compared with fulvic acids from relatively intact peatlands. These properties illustrate that long-term agricultural use with high inputs results in increased aromatic structures and a further humification of dissolved fulvic acids due to very strong peat decomposition compared with relatively intact peatlands. Synchronous fluorescence spectra also indicate the higher level of aromatic structures within fulvic acids isolated from sites with long-term agricultural use (high peat decomposition) compared with a land use history resulting in a lower peat decomposition. The different sources of fulvic acids in surface water (precipitation, runoff, interflow, groundwater) are the main reason for these effects not being detected in fulvic acids isolated from surface water. Short-term changes in land use characterized by a transition from crop farming to an unimproved grassland were found not to affect the spectroscopic properties of dissolved fulvic acids. A humification index deduced from the synchronous fluorescence spectra is proposed. We have strong evidence that dissolved humic substances indicate changes in the environmental conditions (both anthropogenic and natural) of wetlands with a high proportion of organic soils.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 47 (1999), S. 219-238 
    ISSN: 1573-515X
    Keywords: dissolved humic substances ; FTIR spectroscopy ; land use history ; peat ; synchronous fluorescence spectroscopy ; UV/VIS spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The elemental composition and spectroscopic properties of dissolved fulvic acids isolated from different sampling media (topsoil, ground and surface water) of a natural fen area (high portion of organic soils) were examined to reveal the effects of land use history. These effects need to be known if dissolved humic substances are to be a major factor in identifying the impact of present and future changes in land use. Dissolved fulvic acids (topsoil, groundwater) from highly degraded peatlands (due to a long-term agricultural use) exhibit lower C/N ratios, higher absorption in the UV spectra, and higher absorption at 1,620 cm−1 in the FTIR spectra compared with fulvic acids from relatively intact peatlands. These properties illustrate that long-term agricultural use with high inputs results in increased aromatic structures and a further humification of dissolved fulvic acids due to very strong peat decomposition compared with relatively intact peatlands. Synchronous fluorescence spectra also indicate the higher level of aromatic structures within fulvic acids isolated from sites with long-term agricultural use (high peat decomposition) compared with a land use history resulting in a lower peat decomposition. The different sources of fulvic acids in surface water (precipitation, runoff, interflow, groundwater) are the main reason for these effects not being detected in fulvic acids isolated from surface water. Short-term changes in land use characterized by a transition from crop farming to an unimproved grassland were found not to affect the spectroscopic properties of dissolved fulvic acids. A humification index deduced from the synchronous fluorescence spectra is proposed. We have strong evidence that dissolved humic substances indicate changes in the environmental conditions (both anthropogenic and natural) of wetlands with a high proportion of organic soils.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Glycoconjugate journal 14 (1997), S. 785-793 
    ISSN: 1573-4986
    Keywords: glycoprotein ; glycosylation ; gp120 ; HIV ; MALDI-TOF-MS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Neutral complex-type N-glycans of the envelope glycoprotein 120 of HIV-2, propagated in different host cells, display cell-type specific variations. In order to identify typical structural elements, glycans were analysed by gel filtration, by enzymic sequencing and, in part, by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The characteristic substituents of di- tri- and tetraantennary carbohydrate units thus observed include N-acetyllactosamine repeats, bisecting N-acetylglucosamine and fucose linked to the chitobiose core as well as to N-acetyllactosamine antennae. Each glycoprotein preparation displayed a characteristic set of glycoforms. Abbreviations: endo H, endo-β-N-acetylglucosaminidase H; E-PHA, Phaseolus vulgaris agglutinin E4; GlcNAcOH, N-acetyl-glucosaminitol; gp120/HUT78(MOLT4/Mφ/PBL/U937), external envelope glycoprotein 120 of HIV-2, strain D194, propagated in HUT78 (MOLT4, Mφ, PBL, U937) cells; gu, glucose units; HPAEC, high-pH anion-exchange chromatography; MALDI-TOF-MS, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry; Mφ, human monocytes/macrophages; PBL, human peripheral blood lymphocytes; PNGase F, peptide-N4-(N-acetyl-β-glucosaminyl)asparagine amidase F
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 1999-11-01
    Print ISSN: 0168-2563
    Electronic ISSN: 1573-515X
    Topics: Chemistry and Pharmacology , Geosciences
    Published by Springer
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Multimedia systems 7 (1999), S. 70-90 
    ISSN: 1432-1882
    Keywords: Key words:Sychronization – Multimedia streams – Video server
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract. Multimedia streams such as audio and video impose tight temporal constraints for their presentation. Often, related multimedia streams, such as audio and video, must be presented in a synchronized way. We introduce a novel scheme to ensure the continuous and synchronous delivery of distributed stored multimedia streams across a communications network. We propose a new protocol for synchronized playback and compute the buffer required to achieve both, the continuity within a single substream and the synchronization between related substreams. The scheme is very general and does not require synchronized clocks. Using a resynchronization protocol based on buffer level control, the scheme is able to cope with server drop-outs and clock drift. The synchronization scheme has been implemented and the paper concludes with our experimental results.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-4919
    Keywords: VEGF ; hypertrophy ; spontaneously hypertensive rat ; coronary flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Notes: Abstract Left ventricular hypertrophy (LVH) is often associated with an impaired maximal coronary blood flow and increases the vulnerability of the heart tissue to ischaemia. In this study, the correlation between coronary blood flow and expression of the vascular endothelial growth factor (VEGF) mRNA was investigated. Using both haemodynamic measurements and analysis of mRNA, we have demonstrated that during development of LVH, in spontaneously hypertensive rats (SHR), an impaired maximal coronary flow at 12 weeks of age is associated with low levels of VEGF mRNA. However, in older SHR (32 weeks) with stabilised hypertrophy and a normal maximal coronary flow response, VEGF mRNA levels are increased three-fold. These results suggest that the mechanism for the impaired flow, observed in some types of cardiac hypertrophy, might involve an inadequate growth of the coronary vessels due to insufficient activation of the VEGF gene.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 56 (1967), S. 973-992 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract The facies development of the Jurassic in the subbetic realm of Spain shows many common features on the whole in spite of differences in detail. “Neritic limestone facies“ may be distinguished from “Nodular limestone facies“ and “Limestone-marl-facies“. This paper deals with the stratigraphie range of red nodular limestones and “Limonite Crusts“ as equivalents of the celtiberic “Boundary Oolites“. The occurrence ofNucleata, Pygope andPosidonia in the Subbetic is discussed. There are certain facies relations to the Jurassic of the adjacent celtiberic area and especially to the Jurassic of the Western and Southern Alps.
    Abstract: Résumé Les faciès dans le Jurassique subbétique montrent, malgré des différences dans les détails beaucoup de traits communs. Il faut cependant distinguer entre le « faciès des calcaires néritiques», le « faciès des calcaires noduleux» et le « faciès des marnes et calcaires». La distribution stratigraphique des calcaires noduleux rouges et des « croutes de limonite», qui représentent les équivalents des «oolites limitrophes» celtibériques, est discuté. On commente alors l'existence deNucleata, Pygope etPosidonia dans le Subbétique. On peut constater des relations plus ou moins nettes non seulement avec le Jurassique celtibérique, mais aussi, avant tout, avec le Jurassique alpin occidental et méridional.
    Notes: Zusammenfassung Die fazielle Entwicklung des subbetischen Juras weist trotz Differenzierung im einzelnen viele gemeinsame Züge auf. Grundsätzlich ist aber zwischen einer „Neritischen Kalk-Fazies“ einer „Knollenkalk-Fazies“ und einer „Kalk-MergelFazies“ zu unterscheiden. Auf die stratigraphische Verbreitung der Roten Knollenkalke und die „Limonitkrusten“ als Äquivalente der keltiberischen „Grenzoolithe“ wird näher eingegangen, das Auftreten vonNucleata, Pygope undPosidonia im subbetisehen Jura besprochen. Sowohl zum benachbarten keltiberischen Jura als auch zum west- und südalpinen Jura sind mehr oder weniger deutliche Beziehungen vorhanden.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 98 (1967), S. 852-873 
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract The formation of benzotropolone compounds from catechol and pyrogallol derivatives depends upon the type, size, and position of the substituents in the reactants. Electrophilic substituents can be installed only in the 5-position of pyrogallol without loosing the capability of forming benzotropolones. This behavior is explained by the symmetrical electronic structure of the anion acting as 1.3-dipole. Pyrogallols, substituted in the 4- and 6-position by either methyl-, ethyl- or phenyl-groups, yield benzotropolones with 3-methoxy-o-benzoquinone. Isopropyl- andtert. butyl-groups in the same positions hinder benzotropolone formation because of steric hindrance. It was attempted to clarify the effect of the factors on the reaction mechanism by analysis of mixtures of benzotropolones, formed by oxidative coupling of catechol derivatives with pyrogallol-derivatives. On account of deficient yields this could not be done.
    Notes: Zusammenfassung Die Benzotropolonbildung aus Brenzcatechin- und Pyrogallolderivaten hängt von Art, Größe und Stellung der Substituenten in den Reaktionspartnern ab. Nur in die 5-Stellung des Pyrogallols können elektrophile Substituenten eingebaut werden, ohne daß die Fähigkeit zur Benzotropolonbildung verlorengeht. Dieses Verhalten wird durch die Symmetrie der elektronischen Struktur des als 1,3-Dipol wirkenden Anions erklärt. In 4- und 6-Stellung durch Methyl-, Äthyl- und Phenylgruppen substituierte Pyrogallole liefern mit 3-Methoxy-o-benzochinon Benzotropolone; Isopropyl- undtert. Butylgruppen in den gleichen Positionen verhindern aus sterischen Gründen die Benzotropolonbildung. Es wird versucht, aus der Produktanalyse von Benzotropolongemischen, die durch oxydative Verknüpfung von Brenzcatechinderivaten mit Pyrogallolderivaten hervorgegangen sind, Einblick in die den Mechanismus bestimmenden Faktoren zu erhalten. Verbindliche Aussagen hierüber werden durch die mangelhaften Stoffbildungen unmöglich gemacht.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 364 (1999), S. 737-745 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Gel permeation chromatography (GPC) was applied for recognizing the origin of groundwater humic and fulvic acids. GPC was performed with Fraktogel TSK HW-50 in 0.1 M NaCl, pH 8.5 (0.05 M phosphate buffer), 1 mM EDTA, with 10% by volume methanol added. Humic substances from groundwaters and sediments of four different aquifer systems in Germany were isolated, purified and characterized. Both UV/Vis and fluorescence detection were applied. UV/Vis detection was found to be more powerful in identifying differences between the various humic and fulvic acids. The four aquifer systems investigated (“Gorleben”, “Fuhrberg”, “Franconian Albvorland” and “Munich”) differed from one another with respect to hydrological and geochemical conditions. The results showed that the GPC-elution behavior reflects the geochemical environment and origin (source material and generation process) of aquatic humic and fulvic acids.
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