ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Isotope shifts in the atomic spectrum of xenon and nuclear deformation effects (1974)
    Springer
    The European physical journal 270 (1974), S. 113-120 
    Details
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Optical isotope shifts of four lines in the atomic spectrum of xenon have been measured using enriched samples of all stable xenon isotopes. The spectrograms were recorded with the aid of a pressure-scanned Fabry-Pérot interferometer and analysed by digital data techniques. The measured isotope shifts are shown to be self-consistent by means of a King plot. An estimate of the specific mass effect is given and the changesδ 〈r 2〉 of the mean square radius of the nuclear charge distribution are extracted from the measured shifts. These changesδ 〈r 2〉 are discussed in terms of the nuclear deformation parameterβ 2. The results for the deformation of the stable even xenon isotopes are shown to be in good agreement with the systematic of deformation found for the neighbouring elements from Coulomb excitation experiments.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01677442
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Preparation, stoichiometry and magnetic properties of Cu y Cr2Se4−z Br x spinels with 0.5≲x≲2 (1974)
    Springer
    Applied physics 4 (1974), S. 147-151 
    Details
    ISSN: 1432-0630
    Keywords: Magnetic semiconductors ; Chromium halochalcogenide spinels ; Curie temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The chemical composition of Cu y Cr2Se4−z Br x spinels depends strongly on the preparation parameters. Spinels with 0.8≲y≲1.2, 0.5≲x≲2, and 0≲z−x≲0.2 have been prepared. Whereas the lattice constanta o of these spinels differs only by less than approximately 0.6%, their Curie temperatureT c depends sensitively on the spinel composition. For Cu1.1Cr2Se3.4Bro.46,a o=1.0410 nm andT c=310 K were found to compared witha 0=1.0447 nm andT c=84 K of CuCr2Se2Br2.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00884270
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Maxwell-Gleichunge, Energiesatz und Lagrange-Dichte in der Kontinuumstheorie der Versetzungen (1970)
    Springer
    Acta mechanica 10 (1970), S. 59-66 
    Details
    ISSN: 1619-6937
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Description / Table of Contents: Summary The continuum theory of moving dislocations is mathematically analogue toMaxwell's equations of electrodynamics. This analogy shows that the present linear theory of dislocations is incomplete and must be supplemented by constitutive equations between dynamic and kinematic quantities. The generalized electrodynamics ofMie points the way to a Lagrange density. While, in the static case the stress funtions of the continuum are reaction forces with the task to prevent the moving of dislocations, they become impressed forces in the field of moving dislocations and are connectet with the dislocation density by constitutive equations.
    Notes: Zusammenfassung Die Kontinuumstheorie wandernder Versetzungen steht in mathematischer Analogie zu denMaxwellschen Gleichungen der Elektrodynamik. Diese Analogie zeigt, daß die derzeitige lineare Versetzungstheorie unvollständig ist und durch konstitutive Gleichungen zwischen dynamischen und kinematischen Größen ergänzt werden muß. Die verallgemeinerte Elektrodynamik vonMie weist den Weg zu einer Lagrange-Dichte, die eine Funktion entweder der kinematischen oder der dynamischen Größen ist. Während die Spannungsfunktionen des Kontinuums im statischen Falle Reaktionskräfte sind, werden sie im Felde wandernder Versetzungen eingeprägte Kräfte, die über konstitutive Gleichungen mit den Versetzungsdichten verbunden sind.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01176656
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Über die Verwendung von Graphittiegeln zur Probenpräparation in der Röntgenfluorescenzanalyse (1970)
    Springer
    Fresenius' Zeitschrift für analytische Chemie 250 (1970), S. 317-318 
    Details
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00470986
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Darstellung von LiAl[P(CH3)2]4 und der Silylphosphine H3-x(CH3)xSi—P(CH3)2Frau Professor Margot Becke-Goehring zum 60. Geburtstage gewidmet (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 406 (1974), S. 167-170 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of LiAl[P(CH3)2]4 and Silylphosphines H3-x(CH3)xSi—P(CH3)2By metallation of HP(CH3)2 with LiC4H9 (in diglyme, at -40°C) and the subsequent reaction of the LiP(CH3)2 with AlCl3 the compound LiAl[P(CH3)2]4 is obtained (solution in diglyme). The reactions with H3SiBr, CH3SiH2Br, (CH3(2)SiHBr, and (CH3)3)SiCl results in the formation of H3SiP(CH3)2, CH3SiH2,—P(CH32, (CH3)2)SiHP(CH3)2, and (CH3)3Si—P(CH3)2 in large quantities.
    Notes: Durch Metallierung von HP(CH3)2 mit LiC4H9 in Diglym bei -40°C und anschließende Umsetzung des gebildeten LiP(CH3)2 mit AlCl3 wird das LiAl[P(CH3)2]4 zugänglich (Lösung in Diglym). Die Umsetzung mit H3SiBr, CH3SiH2Br, (CH3)2SiHBr und (CH3)3SiCl führt zur präparativen Darstellung von H3Si—P(CH3)2, CH3SiH2—P(CH3)2, (CH3)2SiH—P(CH3)2 (CH3)3Si—P(CH3)2.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744060207
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Reaktionen zur Bildung von Silylphosphinen des Typs X3-(n+m)(CH3)nHmSi—PH2 (X = F, Cl, Br)Vorbericht: Z. anorg. allg. Chem. 405, 337 (1974). (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 407 (1974), S. 295-304 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of Silylphosphines of the X3-(n+m)(CH3)nHmSi—PH2 Type (X = F, Cl, Br)Reactions of halosilanes with silylphosphines containing PH2-groups are reported. CH3SiHCl—PH2 is obtained by (1) For the synthesis of Cl3Si—PH2 reactions of SiCl4 with CH3SiH(PH2)2, CH3SiH2—PH2 and (CH3)3Si—PH2 are carried out in a manner analogous to that shown in eq. (2) Side reactions are observed. Cl3Si—PH2 is isolated in mixture with SiCl4 and CH3SiHCl—PH2 when the most reactive of the above compounds, CH3SiH(PH2)2 is utilized.
    Notes: Es wird über Reaktionen zwischen Halogensilanen und PH2-haltigen Silylphosphinen berichtet. CH3SiHCl—PH2 wird nach Gl. (1) zugänglich. Zur Bildung von Cl3Si—PH2 wurden Umsetzungen von SiCl4 mit CH3SiH(PH2)2, CH3SiH2—PH2 und (CH3)3Si—PH2 durchgeführt, wobei Reaktionen entsprechend Gl. (2) eintreten. Es treten Nebenreaktionen auf. Beim reaktionsfähigeren CH3SiH(PH2)2 ist die Isolierung von Cl3Si—PH2 im Gemisch mit SiCl4 und CH3SiHCl—PH2 möglich. Unter den Reaktionsbedingungen (50°C) zerfällt Cl3Si—PH2 in PH3 und Si—P-Polymere. SiBr4 reagiert bereits bei Raumtemperatur. Durch Umsetzung mit CH3SiH(PH2)2 werden je nach Reaktionsdauer CH3SiHBr—PH2, Br3Si—PH2 und auch Br2Si(PH2)2 zugänglich. Auch die Reaktion mit CH3SiH2—PH2 führt zum Br3Si—PH2 neben CH3SiH2Br. Mit FSiBr3 bildet CH3SiH(PH2)2 das FSiBr2—PH2 neben CH3SiHBr—PH2, während bei den F-reicheren Derivaten F2SiBr2 und F3SiBr die Disproportionierung in SiF4 gegenüber der Si—P-Spaltung überwiegt. Es werden die NMR-Daten der Verbindungen angegeben.Cl3Si—PH2 decomposes into PH3 and Si—P-polymers under the reaction conditions (50°C). SiBr4 however will react at room temperature. Depending on the time of reaction CH3SiHBr—PH2, Br3Si—PH2 and even Br2Si(PH2)2 are obtained with CH3SiH(PH2)2. Also the reaction with CH3SiH2—PH2 leads to the formation of Br3Si—PH2 in addition to CH3SiH2Br. With FSiBr3, CH3SiH(PH2)2 forms FSiBr2—PH2 together with CH3SiHBr—PH2. In the reaction of the higher fluorinated derivatives F2SiBr2 and F3SiBr the disproportion into SiF4 is found to be preferred to Si—P cleavage and therefore these reactions can not be adequately used. The nmr data are reported.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744070305
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    NMR-Untersuchungen an Silylphosphinen. II. Substituenteneinflüsse in Silyl- und Silylmethylphosphinen (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 409 (1974), S. 137-151 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: NMR Studies on Silylphosphines. II. Effects of Substituents in Silyl- and SilylmethylphosphinesThe influence of the substituents [CH3, H, H3Si, (CH3)3Si] on: chemical shifts of protons and phosphorus nuclei: the 29Si-31P coupling constant; and several proton coupling constants in the nmr spectra of 24 silylphosphines of the series (CH3)xH3-x,Si-PH2, (CH3)xH3-xSi-PHCH3, (CH3)xH3-xSi-P(CH3)2, [(CH3)xH3-xSi]2PH, [(CH3)xH3-xSi]2PCH3, [(CH3)xH3-x,Si]3P has been studied. Empirical methods for the calculation of δ31P and J29Si-31P using bond increments are reported.
    Notes: Es wird der Einfluß der Substituenten [CH3, H, H3Si, (CH3)3Si] auf die chemische Verschiebung der Protonen und der Phosphorkerne sowie auf die 29Si-31P-Kopplungskonstante und auf einige Protonenkopplungen in 24 Silylphosphinen der Gruppen (CH3)xH3-x,Si-PH2, (CH3)xH3-xSi-PHCH3, (CH3)xH3-xSi-P(CH3)2, [(CH3)xH3-xSi]2PH, [(CH3)xH3-xSi]2PCH3, [(CH3)xH3-x,Si]3P anhand der NMR-Spektren untersucht. Es werden empirische Verfahren zur Berechnung von δ31 und J29Si-31P aus Bindungsinkrementen mitgeteilt.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744090203
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Reaktionen mit 4-Amino-5-benzoylthiazolen (1974)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 316 (1974), S. 19-25 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Aryl-4-amino-5-benzoyl-thiazole 2 werden zu 2-Aryl-4-acylamino-5-benzoyl-thiazolen 4 acyliert und in Form ihrer Perchlorate 3 mit Ketomethylenverbindungen bzw. Säureamid-Derivaten zu Thiazolo[4,5-b]pyridinen 5 bzw. Thiazolo[4,5-d]pyrimidinen 6 umgesetzt.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19743160104
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Notiz zur Reaktion von Mandelsäurenitril mit Cyanamid (1973)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 315 (1973), S. 44-46 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyanamid reagiert mit Mandelsäurenitril und Benzaldehyd zum 2-Amino-5-cyan-4,5-diphenyl-Δ2-oxazolin 1, das in Gegenwart von Basen einer Eliminierung zu 2-Amino-4,5-diphenyl-oxazol 2 unterliegt und säurekatalysiert zum 2-Amino-5-cyan-4,5-diphenyl-oxazolidinon 4 hydrolysiert wird.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19733150107
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Heterocyclische Farbstoffe und Vorstufen. XXII. Synthese von Thiophen- und Thiazol-Derivaten durch Reaktion von 1,3-Oxathioliumsalzen mit Nucleophilen (1973)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 315 (1973), S. 497-504 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von 2-arylsubstituierten 1,3-Oxathioliumsalzen 1 mit CH-aciden Nitrilen und Estern sowie Cyanamid lassen sich 3-Amino- bzw. 3-Hydroxythiophene 9, 11, 12 sowie 4-Aminothiazole 10 gewinnen, deren Struktur anhand spektroskopischer Daten bewiesen wird.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19733150316
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...