ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Studies have been made by NMR and ESR spectroscopy to elucidate the reaction mechanism in which the Ti(NEt2)4-AlMe3 catalyst system is involved. The two reaction products of Ti(NEt2)3Me and Al(NEt2)Me2 have been confirmed by NMR spectroscopy when Ti(NEt2)4 is reacted with AlMe3, and two kinds of paramagnetic species have been noted by ESR spectroscopy. It has been found that Ti(NEt2)3Me plays an important role as an active species for the polymerization of styrene.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1973.170111210
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