ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Schwingungsspektrum und Normalkoordinaten-Analyse von Matrix-isoliertem, dimeren BerylliumfluoridDas IR-Spektrum des in einer Neon- und Argon-Matrix isolierten Berylliumfluoriddampfes ergibt vier Frequenzen, die versuchsweise BeF4 zugeordnet werden. Mit Hilfe einer Normalkoordinaten-Analyse werden Frequenzen und Amplituden der Schwingungen berechnet.
Notes:
The infrared spectra of the beryllium fluoride vapor species isolated in matrices of neon and argon were obtained in the range (2000-190) cm-1. Four frequencies were identified as belonging to the dimer Be2F4. Assuming the latter to have a planarbridge structure of D2h symmetry, the frequencies in a neon matrix were tentatively assigned. A normal coordinate analysis of the dimer molecule is presented together with the calculated vibrational frequencies and the calculated mean amplitudes of vibration.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19744100213
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