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  • Physical Chemistry  (3)
  • 1970-1974  (3)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Pyrolysis of alkyl nitrites (RONO) (1974)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 6 (1974), S. 945-949 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550060615
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    The CH3—NO bond dissociation energy (1973)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 5 (1973), S. 1067-1069 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550050615
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  • 3
    Electronic Resource
    Electronic Resource
    Heats of formation of C1—C4 alkyl nitrites (RONO) and their RO-NO bond dissociation energies (1974)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 6 (1974), S. 877-885 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The heats of formation of C3 and C4 alkyl nitrites (RONO) have been determined via their heats of combustion by bomb calorimetry, thereby providing a complete set of values of ΔHºf for C1-C4 alkyl nitrites. The experimental values are in excellent agreement with values derived from group additivity rules. For branched compounds these calculations involve corrections for gauche interactions. In these cases, the gauche interactions are reflected in the activation energies E1 determined by recent kinetic studies, required for breaking the RO-NO bond. The heats of formation of the alkoxy radicals involved together with ΔHºf(NO) = 21.6 kcal/mole leads to the result D(RO-NO) = 41.5 ± 1 kcal/mole. The concordance between D(thermochemical) and D(kinetic), unlike previous kinetic studies, implies that E2 = 0 ± 1 kcal/mole.
    Additional Material: 10 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550060610
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