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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 1749-1770 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The amount of residual n-pentane in expandable polystyrene bead foam (PSBF) has an effect on the strength and dimensional stability of the foam. Data were needed to determine how fast the residual n-pentane could be removed to enhance the properties of PSBF. An experiment was designed to determine the diffusivity of n-pentane through PSBF at various temperatures. Mathematical models based on the appropriate diffusion differential equations were then used to predict n-pentane concentrations in in cylinders of PSBF. The diffusivity of n-pentane through PSBF was found to have a magnitude of 1×10-8 to 1×10-6 cm2/sec and to vary with temperature, foam density, n-pentane concentration, and foam structure.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 993-1002 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectra of pteridin-4(3H)-one and all its mono-, di- and tri-C-methyl derivatives are recorded. Spectra of 3-methoxypteridin-4(3H)-one and four of its mono- and dimethyl derivatives are also recorded.Pteridin-4(3H)-one fragments mainly by loss of CO and HCN in either order. Methyl substitution in the pyrazine ring leads to that ring fragmenting in preference to the oxygen bearing pyrimidine ring. Elucidation of fragmentation pathways was facilitated by changes in peak positions with changing methyl substitution patterns.3-Methoxypteridin-4(3H)-ones fragment mainly through initial loss of CH2O, but the ions so produced break down differently from isomeric molecular ions of pteridin-4(3H)-ones. Several fragmentation pathways are discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 447-452 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectra of 3-hydroxypteridin-4-one and five of its mono-and di-methyl derivatives are recorded. Fragmentation of the non-methyl compound (I; R1 = R2 = R3 = H) occurred mainly by successive losses of NO, CO, HCN and HCN. Changes in m/e values of the major peaks with methyl-substitution pattern in the derivatives were consistent with the proposed fragmentation pattern. Several minor fragmentation pathways were also observed but all involved an initial loss from the oxygen containing ring.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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