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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 2213-2222 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The rate of polymerization of a methacrylate monomer was influenced by the molar ratio of benzoyl peroxide to an aromatic tertiary amine accelerator when the product of the concentrations of these was kept constant. The maximum rate, measured as the minimum gel time, occurred in monomer solutions containing about 1.5 moles of peroxide per mole of amine.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 9 (1974), S. 195-203 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1,2-Diaminoethane and 2-aminoethanol-1 were added to the isobutane plasma of a chemical ionization mass spectrometer. The resulting reactant gas mixture did not react with additives containing a single oxygen functional group. Addition reactions were observed with some additives containing multiple oxygen functions. Additives containing nitrogen functions were protonated by the reactant mixture. The relative proportion of protonation to addition depended on the ability of the additive to chelate the reactant ion and on the basicity of the additive. This use of 1,2-diaminoethane and 2-aminoethanol-1 provides a convenient method of varying the reactivity of the plasma in a chemical ionization source.
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 253-265 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Radiopaque glass-resin composites were made for evaluation as denture base materials. The addition of silane-treated, radiopaque, powdered glass to clear poly(methyl methacrylate) resulted in composites that had greater optical translucency than commercially available pink denture base resins. These formulations could be pigmented and opacified to produce materials that simulated oral soft tissues in color and translucency.Other composites were made using various monomer, polymer and glass combinations. Those made from mixes of BIS-GMA, methyl methacrylate, poly(methyl methacrylate), and radiopaque glass had excellent translucency but handling characteristics were less than ideal.Removal of very small glass particles (less than a few μm) appeared to improve optical translucency.A radiographic survey of 12 specimens that contained from 29 to 57% of the radiopaque glass, indicated that all had sufficient radiopacity to aid in localization of swallowed or aspirated dentures made from such materials.Finishing procedures on composite specimens were more difficult and timeconsuming and did not produce surfaces as smooth as those obtained on poly(methyl methacrylate). The finished surfaces felt smooth to the tongue but might stain more easily in the mouth.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 245-252 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The need for esthetic and functionally acceptable radiopaque denture base materials is reflected by numerous reports of patients who ingested or aspirated portions of dentures and reports of difficulties encountered in the removal of these dentures because they could not be located radiographically.The type of denture most commonly ingested or aspirated is a maxillary partial consisting of a palatal piece to which is attached one or more anterior teeth. It may or may not have clasps. Ingestion or aspiration of the foreign body commonly occurs when either broken or ill-fitting dentures are being worn. Few cases have been reported where patients swallowed portions of complete dentures.Previous attempts at providing radiopacity have included addition of heavy metal salts or radiopaque inserts to denture base resins. None of these attempts has been entirely successful.Elimination of dentures as foreign bodies requires a greater effort toward preventive measures by the dentist and the patient. When dentures are swallowed or inhaled, the dentist should immediately seek medical assistance for the patient. The common symptomless period following ingestion or aspiration should not lead the dentist to believe that there will not be serious subsequent complications.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 335-357 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Physical properties were determied for radiopaque composite denture base materials consisting of poly (methyl methacrylate) as thematrix and 30, 40, and 50% by weight fo a singlane-treated barum fluoride-containing glass powder as the reinforcing filler. Specimens without glass were include for comparision.All of the materials met the requirements of Amerrican ental Association Specification No. 12 for Denture Base Polymer except that t6he material containing 50% glass had less deflection than the minimum required at the 5000-gm load in transverse testing.There was little or no difference among thematerials with respect to hardness, in denation resistance, water sorption, color stability, and resistance to drop impact.Addition of glass of the 30% level decreased the transevers strenght while 50% means with no glass. In general, the addition of glass increased the time to reach only slight effect on densities, and Young's, bulk, shear, and flexural moduli, had only slight effect on solubility and decreased the cold-cure repairability and the coefficient of linear thermal expanision.The solubility of the glass power was aboutfour times that of powdered porcelain teeth after 24 hr, and totaled 0.55% afeter 5 days.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 359-371 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Technic dentures were made using composite base materials containing 30,40, and 50 weight % of a silance-treated, readiopaque, powdered glass as the reinforcing filler and poly (methyl methacrylate) as the matrix. Dentures containing no glass were included for comparison. Molar-to-molar dimensional changes, effects of silance treatment fo the procelain teeth and handling and finishing characteristics were determined.Dentures containing glass had less dimensional change during curing and subsequent water storage than those without glass. Thick upper dentrues exhibited the least change and thin lowers, the most. The Differences in the magnitudes of the changes would not be clinically noticeable.Silance treatment fo the procelain teeth in thick upper dentures resulted in breakage of theposterior teeth in almost all instances. posterior teeth also freactured in thick upper dentures containing 40 and 50% of the silance-treated glass even though the teeth were not treatedwith silance.Mixing and molding properties of the composite materials, while acceptabgle, were slightly inferior to thematerial containing ono glass. Finiching characteristics were definitelyinferior in that it was more difficult and time-consuming to attain the fial surfaces and these surfaces were not as smooth as smooth as those in dentures without glass.
    Additional Material: 4 Ill.
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