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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 3361-3373 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The melt rheology of high density polyethylene was investigated. Linear viscoelasticity, capillary flow properties, and molecular weight parameter were measured with a plate relaxometer, capillary rheometer, and gel permeation chromatography, respectively. Intimate correlations among the slope of relaxation modulus curve, non-Newtonian flow behavior, Barus effect, and molecular weight parameter, Mz(Mz+1)/Mw, respectively, were found.
    Additional Material: 14 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 11 (1973), S. 2113-2122 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A new crystal modification was found in poly(ethylene oxide) stretched about two-fold after necking at room temperature. An x-ray diffraction analysis indicated that the planar zigzag molecule passes through a triclinic unit cell with parameters α = 4.71 Å, b = 4.44 Å, c (fiber axis) = 7.12 Å, α = 62.8°, β = 93.2°, and γ = 111.4°. The space group is P1-Ci1. Packing of the molecule is very similar to that of monoclinic polyethylene.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 10 (1972), S. 2363-2378 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The structure of poly-1,3-dioxolane, [—OCH2O—(CH2)2—]n was studied by x-ray diffraction and infrared spectroscopy. Three crystal modifications were found. The crystal structure of modification II was determined: four molecular chains of glide type pass through the orthorhombic unit cell; Pbca-D2h15, a = 9.07 Å, b = 7.79 Å, and c (fiber axis) = 9.85Å. The molecular conformation is The molecular chain consists of regular head-to-tail sequences. This fact shows that the ring opening of 1,3-dioxolane occurs exclusively at the same type of CO bond in the cationic polymerization, just as in the case of 1,3-dioxepane.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 6 (1974), S. 487-491 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Carbon-13 NMR spectra of all-trans retinal1 and vitamin A1 were measured by the pulse Fourier transform method in CCl4. All peaks in these spectra were assigned from considerations of chemical shifts, half proton-decoupled spectra, spin-lattice relaxation times and induced chemical shift by the addition of shift reagent. The carbon-13 NMR spectrum was also measured for all-trans retinal1 which had been exposed to the sunlight for three hours, and the induced isomer was proposed to be 11-s-cis retinal1.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 1073-1087 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A convenient pressure apparatus was designed for crystallization of high polymers under hydrostatic pressure up to 5000 atm. Melt crystallization as well as heat treatment under various temperatures and pressures was carried out on several polymers, and the effects of pressure on the molecular and crystal structures of the samples are discussed. Heat treatment of syndiotactic polypropylene under high pressure yields a new crystal modification rather than the previously known helix and planar zigzag modifications. Of the three modifications of poly(vinylidene fluoride), modification III was found as a high-pressure phase for specimens in the unoriented state, while modification I was obtained as the most stable one on heat treatment of oriented specimens under high pressure. Heat treatment under high pressure converts ordinary isotactic poly-4-methylpentene-1 with a lower density than the noncrystalline value, to a new crystal modification with higher density. As is reasonable, the dense modification is stable in a high-pressure range. For these three cases, the orientation of specimens was found to remain unchanged during the transitions, which must therefore occur in the solid state.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 513-518 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 11 (1973), S. 233-248 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystal structure of α-gutta percha has been determined by x-ray diffraction. The unit cell parameters are a = 7.98 Å, b = 6.29 Å, c (fiber period) = 8.77 Å, and β = 102.0° (monoclinic). The space group is P21/c-C2h5. Two molecular chains of nearly trans-CTS-trans-CTS̄ conformation pass through a unit cell; C, T, S, and S̄ being the cis, trans, and two types of skew forms, respectively. The constrainedle astsquares method was modified so that the order of the least squares matrix could be reduced and was applied to the refinement of the crystal structure.
    Additional Material: 9 Ill.
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  • 8
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A kinetic study has been made of the polymerization of methyl methacrylate (MMA) initiated by a charge-transfer complex of poly-2-vinylpyridine (electron donor) and liquid sulfur dioxide (acceptor) in the presence of carbon tetrachloride. It is concluded that the polymerization proceeds through free-radical intermediates, as with the pyridine-liquid sulfur dioxide complex system. The association constants K of acceptor and polymer electron donors which range widely in their molecular weight were determined spectrophotometrically, and it has been found that both K and overall rate of polymerization Rp of MMA decrease with increasing molecular weight of polymer donor; contrary to this, molecular weight of PMMA formed increases with increasing molecular weight of the polymer donor. Other kinetic behaviors was essentially the same as in the pyridine-liquid sulfur dioxide system, i.e., Rp is proportional to the square root of the concentration of the complex and to the 3/2-order of the monomer concentration; Rp is clearly sensitive to the carbon tetrachloride concentration at low concentration of carbon tetrachloride, but for a higher concentration it is practically independent of the carbon tetrachloride concentration. It has been deduced from a kinetic mechanism for the initiation that a primary radical may be produced from the reduction of carbon tetrachloride by an associated complex consisting of liquid sulfur dioxide-polymer donor and the monomer.
    Additional Material: 11 Ill.
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