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  • 2000-2004  (93)
  • 1970-1974  (15)
  • 1965-1969  (11)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 71 (2000), S. 477-483 
    ISSN: 1432-0630
    Keywords: PACS: 68.35.Ja; 78.47.+p; 82.65.-i
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. One of the major goals in physical chemistry is to obtain a microscopic understanding of chemical reactions. Recent developments in femtosecond laser techniques provide the opportunity to resolve the timescale of elementary steps of chemical reactions at surfaces. This is exemplified for the femtosecond laser-induced oxidation of CO on Ru(001). Among other adsorbate-specific probes vibrational sum-frequency generation spectroscopy offers the possibility to monitor adsorbates or reaction intermediates directly at the surface. Recently, we have employed this technique to investigate the dynamics of the CO-stretch vibration of CO adsorbed on Ru(001) after optical excitation leading to CO desorption.
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 9888-9897 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Irradiation of a Ru(001) surface covered with CO using intense femtosecond laser pulses (800 nm, 130 fs) leads to desorption of CO with a nonlinear dependence of the yield on the absorbed fluence (100–380 J/m2). Two-pulse correlation measurements reveal a response time of 20 ps (FWHM). The lack of an isotope effect together with the strong rise of the phonon temperature (2500 K) and the specific electronic structure of the adsorbate–substrate system strongly indicate that coupling to phonons is dominant. The experimental findings can be well reproduced within a friction-coupled heat bath model. Yet, pronounced dynamical cooling in desorption, found in the fluence-dependence of the translational energy, and in a non-Arrhenius behavior of the desorption probability reflect pronounced deviations from thermal equilibrium during desorption taking place on such a short time scale. © 2000 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 36 (1971), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: SUMMARY— Excellent retention of fresh flavor quality in a series of freeze-dried foods of plant and animal origin was achieved in “zero” oxygen headspace, using an atmosphere of 5% hydrogen in nitrogen with a palladium catalyst. Freeze-dried, precooked carrots, sweet potatoes, green beans, peas, spinach, white potatoes, peaches, apricots, chicken, pork, beef, beef stew, chicken stew and shrimp were investigated for oxygen uptake, flavor quality and some for consumer acceptability. The rate of oxygen uptake during storage was greater in the animal products than in the plant products studied. For oxygen-sensitive products such as carrots and sweet potatoes, loss of quality was observed in packs with headspace containing as little as 0.5% oxygen within 1 month at 100°F reflected in the lower scores given by a technological panel. A flavor profile panel reported that all the foods packed with 5% hydrogen in nitrogen with palladium catalyst had aroma and flavor amplitudes after storage at 100°F for 6 months comparable to the original products. Randomly selected untrained consumer test panels preferred the foods packed in “zero” oxygen to those in 2% oxygen after brief storage at 100°F. This preference persisted throughout the test year.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 6022-6024 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ba2Cu3O4Cl2 is a two-dimensional quantum antiferromagnet with two Cu sublattices showing a small spontaneous magnetization M0. A group theoretical analysis shows that M0 may be due to (i) induced magnetization in the Cu II sublattice or (ii) spin canting of the Cu I moments, i.e., weak ferromagnetism (WFM). In case (i) the interaction is of pseudodipolar type. In case (ii) the Cu I moments are subject to some kind of anisotropy. The main reason for the occurrence of M0, compared to similar high-Tc cuprates related structures, is that the center between two Cu I moments is not an inversion center. Ba3Cu2O4Cl2 behaves like a classical antiferromagnet with a spin-flop transition. For this compound our analysis shows that, in the case where the magnetic and the crystallographic unit cells are identical, the Cu moments of equivalent sites should be parallel and the antiferromagnetic order is related to opposite directions of the moments at different sites. Weak antiferromagnetism but no WFM is permitted, in agreement with the experimental results. © 2000 American Institute of Physics.
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  • 5
    ISSN: 1434-601X
    Keywords: PACS. 13.60.Le Meson production – 25.20.Lj Photoproduction reactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: Double neutral pion photoproduction from the proton has been measured at MAMI for photon energies between threshold and 820 MeV. The reaction was identified by an invariant mass and missing mass analysis. From threshold up to 370 MeV the total cross-section does not exceed 30 nb. For higher energies it shows a smooth rise until it reaches a maximum of about 10 μb at E γ = 740 MeV. Dalitz plots of m 2(π0π0) versus m 2(p,π0) for seven bins of incident photon energy have been analysed. For E γ 〉 610 MeV, a strong contribution of a sequential decay is observed with the Δ(1232)-resonance as intermediate state. A comparison to model calculations shows that these sequential decays presumably originate from the D 13(1520) and also the P 11(1440)-resonance.
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  • 6
    ISSN: 1434-601X
    Keywords: PACS. 13.60.Le Meson production – 25.20.Lj Photoproduction reactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: The photoproduction of two neutral pions from the deuteron has been studied for incident photon energies from 200 MeV to 820 MeV with the TAPS spectrometer at MAMI (Mainz Microtron). The total cross-section was determined and used to deduce the cross-section from the neutron. Due to the good statistical quality of the data Dalitz plots for the three particles in the exit channel (π0π0 N) could be constructed. The invariant mass distributions derived from them are presented in this paper. They indicate that the important reaction mechanism in the second resonance region is a sequential decay pattern involving the population of the Δ(1232)-resonance as an intermediate state.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 123 (2000), S. 409-418 
    ISSN: 1573-2932
    Keywords: environmental law ; legal education ; pedagogy ; regulations ; simulations ; statutes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract All students at the University of Richmond School of Law are required to complete a first-year course in Environmental Law, as an introduction to the strategies and technicalities of statutory and regulatory regimes. This requirement poses special pedagogical challenges for the instructors. How, for example, is the class to address pollution questions regarding diverse media? Which of the many federal and nonfederal statutory provisions deserve the most (and least attention)? How does the instructor hold the attention of, and gain the most effective work product from, students whose major interests lie outside the area of Environmental Law? What is the proper mix of statutory, regulatory, and judge-made (pre- and post-regulatory) law? Our solution has been to craft a unique combination of traditional lectures and readings regarding specific statutes, regulations, and case law; weekly discussion questions that immerse the students in the intricacies of statutory and regulatory provisions; a series of small-group simulations designed to highlight substantive legal points and to place the students in a wide range of legal and extralegal settings (client interviews, appellate argument, advocacy before administrative bodies, negotiation, lobbying public officials, legislative drafting); and periodic written assignments that focus the students' attention on technical legal and public policy issues.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 405 (1974), S. 286-298 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: ESR Studies of Radiation Processes in Phosphate GlassesRadiation processes in phosphate glasses are investigated by ESR and optical measurements. ESR shows a hole-centre in the systems K2O/P2O5 and K2O/MGO/P2O5 which depends on manner and concentration of the cations. Its nature is explained in somewhat a different way than given by BEEKENKAMP or by MIURA and HASEGAWA. Another hole-centre which is independent of cations is discussed in agreement with optical investigations. The electrons set free by radiation react with O2 solved in the glass or with cations. The particels Ag0, Ag2+, Ag+2 have been found and Agn+4 may be present too in the system K2O/MgO/Ag2O/P2O5. The system K2O/MgO/Tl2O/P2O5 shows analogous reactions, but full explanation of the lines could not yet be given.
    Notes: Durch ESR-Untersuchungen und Vergleiche mit optischen Messungen werden Aussagen über die durch Bestrahlung in Phosphatgläsern ablaufenden Vorgänge gemacht. In den Systemen K2O/P2O5 und K2O/MgO/P2O5 wird durch ESR-Messungen ein kationenabhängiges Lochzentrum gefunden, dessen Natur in Abweichung von den Modellen nach BEEKENKAMP und nach MIURA u. HASEGAWA erklärt wird. Ein weiteres kationenunabhängiges Lochzentrum wird in Übereinstimmung mit optischen Untersuchungen gedeutet. Die durch Bestrahlung freigesetzten Elektronen lagern sich an im Glas gelösten Sauerstoff (O2) an oder reagieren mit den Kationen. Im System K2O/MgO/Ag2O/P2O5 werden die Teilchen Ag0, Ag2+, Ag+2 gefunden und Agn+4 wahrscheinlich gemacht. Für das System K2O/MgO/Tl2O/P2O5 gelten analoge Verhältnisse. Eine ausführliche Zuordnung konnte aber dabei noch nicht vorgenommen werden.
    Additional Material: 6 Ill.
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  • 9
    Publication Date: 2000-11-14
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 10
    Publication Date: 2003-09-30
    Print ISSN: 0031-9007
    Electronic ISSN: 1079-7114
    Topics: Physics
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