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  • 2010-2014  (7)
  • 1970-1974  (6)
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 473-480 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectrometric behavior of the di-TMSi derivatives of diamino-,dihydroxy-and aminohydroxynaphthalenes is described. The presence or lack of doubly-charged ions in the mass spectra is correlated with substituent position. Comparison is made with the spectra of the disubstituted benzenes. Other fragmentations are discussed with supporting data from TMSi-d9 derivatized compounds.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 237-240 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes the mass spectra of some di-trimethylsilyl derivatives of aromatic amines. Numerous doubly-charged ions of low relative intensity are found in all spectra. An intense doubly-charged ion is found at m/e [M - 30]/2, whereas the singly-charged counterpart is very small in all cases.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 563-569 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A mass spectrometric study of the trimethylsilyl derivatives of a group of amino-hydroxy, dihydroxy and dicarboxydiphenyls has disclosed that these compounds produce a number of intense doubly-charged ions ([M - 30]/2, 5 to 27%), for which the singly-charged ions are low or absent. The derivative of 4,4′-dicarboxydiphenyl yields five such doubly-charged ions with relative intensities ⋝ 3%. The fragmentation pathways for this compound have been studied by the formation and mass spectrometry of the trimethylsilyl-d9 derivative.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2014-12-13
    Description: Current earthquake early warning (EEW) systems lack the ability to appropriately handle multiple concurrent earthquakes, which led to many false alarms during the 2011 Tohoku earthquake sequence in Japan. This paper uses a Bayesian probabilistic approach to handle multiple concurrent events for EEW. We implement the theory using a two-step algorithm. First, an efficient approximate Bayesian model class selection scheme is used to estimate the number of concurrent events. Then, the Rao-Blackwellized Importance Sampling method with a sequential proposal probability density function is used to estimate the earthquake parameters, that is hypocentre location, origin time, magnitude and local seismic intensity. A real data example based on 2 months data (2011 March 9–April 30) around the time of the 2011 M 9 Tohoku earthquake is studied to verify the proposed algorithm. Our algorithm results in over 90 per cent reduction in the number of incorrect warnings compared to the existing EEW system operating in Japan.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 5
    Publication Date: 2014-03-21
    Description: This study lays the groundwork for a new generation of earthquake source models based on a general formalism that rigorously quantifies and incorporates the impact of uncertainties in fault slip inverse problems. We distinguish two sources of uncertainty when considering the discrepancy between data and forward model predictions. The first class of error is induced by imperfect measurements and is often referred to as observational error. The second source of uncertainty is generally neglected and corresponds to the prediction error, that is the uncertainty due to imperfect forward modelling. Yet the prediction error can be shown to scale approximately with the size of earthquakes and thus can dwarf the observational error, particularly for large events. Both sources of uncertainty can be formulated using the misfit covariance matrix, C , which combines a covariance matrix for observation errors, C d and a covariance matrix for prediction errors, C p , associated with inaccurate model predictions. We develop a physically based stochastic forward model to treat the model prediction uncertainty and show how C p can be constructed to explicitly account for some of the inaccuracies in the earth model. Based on a first-order perturbation approach, our formalism relates C p to uncertainties on the elastic parameters of different regions (e.g. crust, mantle, etc.). We demonstrate the importance of including C p using a simple example of an infinite strike-slip fault in the quasi-static approximation. In this toy model, we treat only uncertainties in the 1-D depth distribution of the shear modulus. We discuss how this can be extended to general 3-D cases and applied to other parameters (e.g. fault geometry) using our formalism for C p . The improved modelling of C p is expected to lead to more reliable images of the earthquake rupture, that are more resistant to overfitting of data and include more realistic estimates of uncertainty on inferred model parameters.
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 6
    Publication Date: 2014-06-28
    Description: We present a fully Bayesian inversion of kinematic rupture parameters for the 2011 M w 9 Tohoku-oki, Japan earthquake. Albeit computationally expensive, this approach to kinematic source modelling has the advantage of producing an ensemble of slip models that are consistent with physical a priori constraints, realistic data uncertainties, and realistic but simplistic uncertainties in the physics of the kinematic forward model, all without being biased by non-physical regularization constraints. Combining 1 Hz kinematic GPS, static GPS offsets, seafloor geodesy and near-field and far-field tsunami data into a massively parallel Monte Carlo simulation, we construct an ensemble of samples of the posterior probability density function describing the evolution of fault rupture. We find that most of the slip is concentrated in a depth range of 10–20 km from the trench, and that slip decreases towards the trench with significant displacements at the toe of wedge occurring in just a small region. Estimates of static stress drop and rupture velocity are ambiguous. Due to the spatial compactness of the fault rupture, the duration of the entire rupture was less than approximately 150 s.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 7
    Publication Date: 2013-08-13
    Description: The estimation of finite fault earthquake source models is an inherently underdetermined problem: there is no unique solution to the inverse problem of determining the rupture history at depth as a function of time and space when our data are limited to observations at the Earth's surface. Bayesian methods allow us to determine the set of all plausible source model parameters that are consistent with the observations, our a priori assumptions about the physics of the earthquake source and wave propagation, and models for the observation errors and the errors due to the limitations in our forward model. Because our inversion approach does not require inverting any matrices other than covariance matrices, we can restrict our ensemble of solutions to only those models that are physically defensible while avoiding the need to restrict our class of models based on considerations of numerical invertibility. We only use prior information that is consistent with the physics of the problem rather than some artefice (such as smoothing) needed to produce a unique optimal model estimate. Bayesian inference can also be used to estimate model-dependent and internally consistent effective errors due to shortcomings in the forward model or data interpretation, such as poor Green's functions or extraneous signals recorded by our instruments. Until recently, Bayesian techniques have been of limited utility for earthquake source inversions because they are computationally intractable for problems with as many free parameters as typically used in kinematic finite fault models. Our algorithm, called cascading adaptive transitional metropolis in parallel (CATMIP), allows sampling of high-dimensional problems in a parallel computing framework. CATMIP combines the Metropolis algorithm with elements of simulated annealing and genetic algorithms to dynamically optimize the algorithm's efficiency as it runs. The algorithm is a generic Bayesian Markov Chain Monte Carlo sampler; it works independently of the model design, a priori constraints and data under consideration, and so can be used for a wide variety of scientific problems. We compare CATMIP's efficiency relative to several existing sampling algorithms and then present synthetic performance tests of finite fault earthquake rupture models computed using CATMIP.
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 8
    Publication Date: 1972-01-01
    Print ISSN: 0031-9171
    Topics: Physics
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  • 9
    Publication Date: 1973-01-01
    Description: A new technique to enhance the earthquake resistance of tall reinforced‐concrete bridges is introduced whereby the tall piers are allowed to ‘step’ during a severe seismic attack. This means that each pier is free to rock from side to side with vertical separation of parts of the pier from the supporting foundations. This stepping action limits stresses in the reinforced‐concrete piers to values below the yield levels and this should lead to a substantial reduction in the cost of providing earthquake resistance As part of a feasibility study, a 200 feet‐high stepping pier is defined and its displacements are calculated for the ground accelerations of the 1940 El Centre earthquake, N‐S component. With no damping present the computations give many ‘stepping’ separations of rather large extent. When the effects of internal structural damping are included in the analysis, there is little reduction in the stepping motions at the level of damping expected in the pier. However, when the computations include the effects of some energy‐absorbing devices of a recently‐developed type, installed between the pier and its foundations, the amplitude and number of the stepping cycles are considerably reduced. Copyright © 1973 John Wiley & Sons, Ltd
    Print ISSN: 0098-8847
    Electronic ISSN: 1096-9845
    Topics: Architecture, Civil Engineering, Surveying
    Published by Wiley
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  • 10
    Publication Date: 1974-01-01
    Description: The recent development of a range of hysteretic energy absorbers permits practical shock isolation systems to be incorporated in the bases of a wide range of structures. This isolation gives reduced earthquake loads which may be resisted by the normal lateral strength of the structure. Hence a plastic reserve of earthquake resistance is no longer essential. A wider choice of architectural and structural forms is available with such an isolation system. The structures may be designed to prevent structural and non‐structural damage with a high degree of reliability. The special hysteretic dampers limit the lateral movement of the base of a structure to a few inches. With these small movements the lateral flexibility required for an isolating system can be conveniently provided, for many structures, by rubber bearings. Copyright © 1974 John Wiley & Sons, Ltd
    Print ISSN: 0098-8847
    Electronic ISSN: 1096-9845
    Topics: Architecture, Civil Engineering, Surveying
    Published by Wiley
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