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  • 1975-1979  (19)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 10 (1979), S. 83-87 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Используя соответствующую реакционную модель, смещение двойной связи пропилена на фаязитных цеолитах, протекающее по трем возможным механизмам, обсуждается теоретически. Энергетические кривые были рассчитаны с помощыю расширенной терии Хюккеля. Критически обсиждаются результаты теоретических приближений.
    Notes: Abstract Using an appropriate reaction model, the double bond shift in propene on faujasite zeolites proceeding via three possible mechanisms was theoretically treated. The energy curves were calculated by means of the extended Hückel theory. The results of the theoretical approach are critically discussed.
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  • 2
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Значения постоянной скорости треуголной схемы, определенные нелинейным способом приближения, изменяются систематически в зависимости от концентрации хлористого родорода. Изменение цис-транс избирательности, выраженное как отношение k1c/k1t, указывает на изменение механизма изомеризаций с концентрацией хлористого водорода.
    Notes: Abstract The values of the rate constants of the triangle scheme, calculated by means of a non-linear least-squares method, depend systematically on the HCl concentration. The alteration of the cis-trans selectivity expressed by the ratio k1c/k1t might indicate a change in the mechanism of isomerization with the HCl concentration.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 31 (1975), S. 247-249 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Zusammenfassung Der Titer von Ecdyson und Ecdysteron in Heuschrecken (Locusta migratoria) des V. Larvenstadiums wurde getrennt bestimmt. Ecdysteron herrscht zur Zeit des Titermaximums vor. Durch Injektion von radioaktivem Ecdyson wird gezeigt, dass dies durch ein Ansteigen der Steroid-20-Hydroxylase-Aktivität verursacht wird. Die Ausscheidung von Häutungshormonen mit dem Kot sorgt für das Sinken der Häutungshormon-Konzentration in den Tieren.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Human genetics 〈Berlin〉 32 (1976), S. 43-48 
    ISSN: 1432-1203
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The α1-antitrypsin phenotypes of two Dutch population groups (consisting of 672 and 802 individuals) were determined by the isoelectric focusing technique, which due to its recent development, has been used for the first time in large-scale phenotyping. As in other population studies on the α1-antitrypsin phenotype distribution, Pi M is the most frequently occurring allele. The two investigated groups exhibit remarkable differences, both to other studied groups as well as to each other. The most interesting results are probably the high frequencies of the alleles Pi- and of the recently discovered Pi MN. Comparison with phenotype studies carried out in other populations is also presented.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Human genetics 〈Berlin〉 34 (1976), S. 17-22 
    ISSN: 1432-1203
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary A new variant of α1-antitrypsin has been detected with the aid of isoelectric fucosing on polyacrylamide slab gels. In contrast with many other variants this new α1-antitrypsin allele is found in 10–15% of the phenotypes examined. The electrophoretic properties of the new α1-antitrypsin variant in isofocusing polyacrylamide gels differ only silightly from the most common α1-antitrypsin allele M. On the basis of its electroforetic behaviour we propose the term MN to indicate this new protease inhibitor variant. The isofocusing technique employed, provides an easy to handle, very reproducible method for determining the α1-antitrypsin phenotype and can be employed for large scale screening.
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  • 6
    ISSN: 1432-2048
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary The mechanism of action and the regulatory properties of glutamate dehydrogenase from pea seedlings (Pisum sativum, var. Späths Violetta) have been investigated by using a highly purified preparation of the enzyme. Kinetic experiments show that the binding of the coenzyme (NAD+ or NADH) and the substrate (L-glutamate or α-ketoglutarate) is sequential. The formation of a quarternary complex with ammonia as additional substrate is questionable, as can be seen from the kinetic data. The anions of the ammonia source have a strong rate-regulating effect on the NADH reaction. The adenosinphosphates AMP, ADP, and ATP exert an inhibiting effect on both the reductive amination and the oxidative deamination reaction. The former reaction is inhibited half as much as the latter. Dead end inhibition offers a sufficient explanation for this effect. The glutamate dehydrogenase from pea seedlings is not regulated by the energy charge. Zn2+ ions are strong inhibitors of the NADH-reaction; their inhibitory effect on the activity is indirect and can be reversed by addition of ATP. A reaction sequence is formulated.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 27 (1977), S. 1095-1098 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The thermal neutron cross sections for severalα-transitions of the143Nd(n,α) reaction have been measured using a semiconductor surface barrier telescope. The143Nd(n, γα) reaction has been observed. The180Hf(n,α) cross section estimation is given.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 25 (1975), S. 854-858 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An alpha spectrometer based on a telescope consisting of two silicon semiconductor surface barrier detectors is described. The spectrometer has been used to study the α-particle energy spectra of an (n,α)-type reaction and ternary fission of uranium in an energy range 4–30 MeV with a resolution of 85 keV.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 18 (1975), S. 55-67 
    ISSN: 1570-7458
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Résumé Les populations du Psylle Acizzia russellae présentent un déclin brusque en été qui coïncide avec l'élévation de la température. Ceci peut paraître surprenant chez une espèce qui est adaptée depuis longtemps à vivre en association avec une plante semi-désertique (Acacia karroo); aussi on a entrepris une étude de la résistance de cet insecte aux élévations de température en tenant compte du rôle de la plante-hôte. La survie des nymphes et des imagos isolés de la plante-hôte dépend d'une interaction entre le déficit de saturation et la température. Les Psylles survivent à des températures plus élevées lorsqu'ils sont sur leur plante-hôte; par ailleurs les “larves” du 5ème stade sont moins sensibles aux températures élevées que les 4 premiers stades larvaires, ces derniers étant eux-mêmes moins sensibles que les adultes. En utilisant des larves du dernier stade sur leur plante-hôte, soumises à des températures critiques, de 43° et 46° et en rapportant les variations de survie au déficit de saturation, on obtient une courbe en V inversée, le pourcentage de survie étant plus faible pour les valeurs les plus basses et pour les valeurs les plus élevées de déficit de saturation. Les conclusions qu'on peut tirer sont: 1) pour de faibles déficits de saturation, le refroidissement obtenu par évaporation, au niveau de la plante ou de l'insecte, est insuffisant pour ramener la température au-dessous de la température létale supérieure. 2) pour les valeurs moyennes du déficit de saturation, le refroidissement dû à l'évaporation évite d'atteindre ce seuil de la température létale, sans cependant entraîner une mortalité par perte d'eau trop élevée (la survie est maximum). 3) pour les hautes valeurs du déficit de saturation, la mortalité s'accroît précisément en conséquence de cette dessiccation des organismes, bien que le refroidissement par évaporation soit en principe plus efficace. La survie se révèle d'ailleurs meilleure sur des plantes abondamment irriguées que sur celles non irriguées, le pourcentage de survie des Psylles décroît brusquement lorsque la plante subit un besoin en eau accrue. Le refroidissement au niveau de la plante a été étudié à l'ombre, au soleil et sous une irradiation artificielle aux infra-rouges; ce refroidissement est en étroite corrélation avec le déficit de saturation, de sorte que le refroidissement maximum d'environ 7o est obtenu pour le déficit de saturation le plus élevé. Des expériences cherchant à établir le rôle de l'évaporation au niveau de l'insecte et sa part dans l'abaissement de la température, n'ont pas permis d'aboutir à des conclusions valables. Le relevé des populations naturelles du Psylle A. russellae, sur une période de 3 ans, montre une réduction estivale, semblable à celle connue chez d'autres Psyllides. Les résultats présentés ici soulignent l'importance de la plante-hôte dans l'action de la température sur le niveau des populations, les effets directs à court terme des températures élevées étant de peu d'importance sur la dynamique des populations de ce Psylle.
    Notes: Abstract The psyllid, Acizzia russellae, survived higher temperatures on the host plant (Acacia karroo) than off it and our results demonstrated an interaction between saturation deficit (S.D.) and temperature in causing death. With psyllids exposed to critically high temperatures on the plant a characteristic inverted “V” shaped survival curve, plotted against S.D., was realised, suggesting that (i) at low S.D.'s the insects were suffering heat death: evaporative cooling from the host plant, and perhaps the insects, failing to lower temperatures below the upper lethal limit; (ii) at moderate S.D.'s survival was greatly increased: evaporative cooling resulting in lowered body temperatures but without lethal desiccation; (iii) at high S.D.'s, in spite of more effective evaporative cooling, desiccation caused death. Significant evaporative cooling by the leaves of A. karroo was measured, but experiments designed to resolve the relative roles of evaporative cooling by the plant and the insect in reducing temperature-induced mortality were inconclusive. The influence of direct short-term temperature effects on the population fluctuations of the psyllid in the field is discussed.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 9 (1978), S. 1-7 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Было исследовано влияние хлористого водорода на кинетику изомеризации бутена, катализированной RhCl3 · 3H2O в широкой области концентраций хлористого водорода. Очевидно сам HCl участвует в механизме изомеризации в виде кокатализатора. Кроме того HCl изменяет равновесие активации катализатора. Предлагается уравнение для описания действия хлористого водорода.
    Notes: Abstract A study has been made of the influence of HCl on the kinetics of butene isomerization catalyzed by ethanolic rhodium trichloride over a wide range of HCl concentrations. Apparently HCl itself participates in the isomerization as a cocatalyst, and it shifts the equilibrium of the catalyst activation too. An equation for the description of the effect of HCl is suggested.
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