ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of O3 with CH3ONO and C2H5ONO were studied using infrared absorption spectroscopy in a static reactor at temperatures between 298 and 352K. Both reactions followed simple second-order kinetics forming the corresponding nitrate: The rate coefficients are given by \documentclass{article}\pagestyle{empty}\begin{document}$$\log _{10} {\rm}k_1 ({\rm cm}^{\rm 3} /{\rm molc} \cdot {\rm sec}) = (- 12.17 \pm 0.23) - (\frac{{5315 \pm 172}}{{2.303{\rm}T}})$$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$\log _{10} {\rm}k_2 ({\rm cm}^{\rm 3} /{\rm molc} \cdot {\rm sec}) = (- 15.50 \pm 0.16) - (\frac{{2351 \pm 116}}{{2.303{\rm}T}})$$\end{document}.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550080212
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