ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Salts of Halogenophosphoric Acids. XII. On Preparation and Properties of Acetyl Fluorophosphates and the Condensation of Alkali Hydrogenmonofluorophosphates with Acetic AnhydrideThe reaction of alkali hydrogenmonofluorophosphates, M[HPO3F], (M = K, NH4), and acetic anhydride forms acetyl monofluorophosphates, M[PO3FCOCH3], at lower temperatures, which were conversed in difluorodiphosphates, M2[P2O5F2], at higher temperatures. It is reported the constitution and the reaction behaviour of the acetyl monofluorophosphates.
Notes:
Die Umsetzung von Alkalihydrogenmonofluorophosphaten, M[HPO3F] (M = K, NH4), mit Acetanhydrid führt unter milden Bedingungen zur Bildung von Acetylmonofluorophosphaten M[PO3FCOCH3] (I), die bei höheren Temperaturen in Difluorodiphosphate, M2[P2O5F2], übergehen. Über Konstitution und Reaktionsverhalten von I wird berichtet.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794520109
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