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  • 1975-1979  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 11 (1979), S. 301-305 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Наряду с другими продуктами были получены высшие олефины линейной структуры в олигомеризации этилена при низкой температуре с селективностью 30–58 вес.% и линейностью до 85%. Активированные титан- и цирконий-содержащие комплексы, используемые в качестве катализаторов, были закреплены на SiO2 через связанные на поверхности бидентатные S- и N-содержащие лиганды. При этом первые оказались лучшими, чем последние, с точки зрения качества продукта.
    Notes: Abstract Besides other products, linear middle-range olefins were obtained in the low temperature oligomerization of ethylene with a selectivity of 30–58% and a linearity up to 85%. Activated ticanium and zirconium complexes as catalysts were attached to SiO2 through surface bounded bidentate S- and N-containing ligands, the former being superior to the latter with respect to product quality.
    Type of Medium: Electronic Resource
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