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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 434 (1977), S. 192-200 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Raman Spectroscopic and Ultracentrifugal Measurements of the Hydrolysis of Dodecatungstophosphoric AcidThe hydrolysis and the stability of dodecatungstophosphoric acid in aqueous and aqueous sodium chloride solutions were investigated by means of Raman-spectroscopic and ultracentrifugal measurements. The scheme of hydrolysis appears to be the most probable: (see „Inhaltsübersicht“).The stability of H3[PW12O40] in aqueous solutions is reduced remarkably when sodium chloride is added as a supporting electrolyte.
    Notes: Die Hydrolyse und die Stabilität der Dodekawolframatophosphorsäure wurde in wäßriger sowie in wäßriger NaCl-haltiger Lösung mit Hilfe ramanspektroskopischer und durch Ultrazentrifugen-Messungen untersucht.Nach den Meßerjergebnissen erscheint folgendes Hydrolyseschema am wahrscheinlichsten : Die Stabilität von H3[PW12O40] in wäßriger Lösung wird durch Zusatz von NaCl als Fremdelektrolyt wesentlich verringert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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