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  • Chemistry  (8)
  • Computer Systems
  • 1975-1979  (5)
  • 1935-1939  (1)
  • 1925-1929  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 173 (1928), S. 125-136 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Wenn ozonisierter Sauerstoff durch Lösungen von Eosin, Uranin, Safranin, Neutralrot, Rhodamin B, Thioflavin, Cartharamin Rhodamin B. J. N. N., Erythrosin und Aesculin geleitet wird, beobachtet man ein Leuchten.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 186 (1929), S. 154-158 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Wenn zahlreiche fluorescierende oder nicht fluorescierende Farbstofflösungen durch Wasserstoffperoxyd in Gegenwart von Ferrosulfat oxydiert werden, tritt ein Glimmen auf, das im dunklen Raume zu erkennen ist.2. Die Wellenlangen der Glimmerscheinung bei der Oxydation einiger fluorescierender Fnrbstoffe durch ozonisierten Sauerstoff sind gemessen worden.3. Kieselsaure mit etwas adsorbiertem Neutralrot zeigt in einer Suspension in Äthylallrohol bei Behandlung mit ozonisiertem Sauerstoff eine Glimmerscheinung.4. Wenn kleine Mengen eines Farbstoffes, der gutes Glimmen zeigt , rnit einem anderen Farbstoff von schwachem Glimmvermogen gemischt werden, so liefert das Gemisch bei Behandlung mit Ozon ein starkeres Glimmen als der schwächer glimmende Farbstoff allein.5. Steigerung der Temperatur führt zur Verstarkung des Glimmens bei der Oxydation von Reduktionsmitteln durch Ozon oder Wasserstoffperoxyd.6. Zunahme der Konzentration der Reduktionsmittel verursacht eine Steigerung der Glimmintensitat bis zu einem Grenewert. Wird die Konzentration weiter gesteigert, so schwacht sich das Glimmen ab und hört schließlich auf.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 72 (1978), S. 57-66 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(N-vinylcarbazol) wurde mit verschiedenen Reagenzien sulfoniert und die Ionenaustauschkapazität der erhaltenen Harze bestimmt. Eine maximale Kapazität von 4,5 meq · g-1 des trockenen Harzes wurde durch 10stündige Reaktion mit 98,8proz. H2SO4 bei 30°C erhalten. Die pH-Titrationskurven lassen einen starken monofunktionellen Kationenaustauscher mit einem pK-Wert von 2,2 erkennen. Das Harz zeigt eine mäßige Austauschgeschwindigkeit mit NaCl und ist bis zu 250°C thermisch stabil.
    Notes: Poly(N-vinyl carbazole) was sulfonated with different sulfonating agents and ion exchange capacities of the resins produced were evaluated. A maximum capacity of 4.5 meq · g-1 of dry resin was realized when sulfonation was done with 98.8% H2SO4 at 30°C for 10 h. The pH titration curves reveal the nature of a strong monofunctional cation exchanger with a pK value of 2.2. The resin exhibits a moderate rate of exchange with NaCl and is thermally stable up to ca. 250°C.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 73 (1978), S. 53-61 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Kationenaustauscher wurde durch Kondensation von Polyisobutylvinyläther und Furfural hergestellt. Als Katalysator diente konzentrierte Schwefelsäure. Der Austauscher wurde durch Messen der Austauschkapazität, durch Untersuchen seiner thermischen Belastbarkeit und durch Bestimmen seines Verhaltens bei der pH-Titration charakterisiert. Es scheint sich um einen Austauscher mit schwachen Säregruppen zu handlen, die wohl als —COOH-Gruppen vorliegen und durch Oxidation aus den Furfuralgruppen entstanden sein dürften.
    Notes: A cation exchange resin was synthesized from the condensation product of poly(iso-butyl vinyl ether) and furfural by treating it with concentration sulphuric acid. The resin produced was characterized by measuring its total and salt splitting capacities, and by studying its thermal characteristics and behaviour to pH metric titration. The latter suggests the resin to be a weak one possibly containing —COOH groups, which result from the oxidation of the furfural aldehyde group by sulphuric acid.
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 2327-2334 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Cation-exchange resins have been synthesized through the condensation of N-vinylcarbazole and poly(N-vinylcarbazole) with furfural in presence of anhydrous AlCl3 and subsequent sulfonation of the condensates. The resins have been characterized in respect to their polyfunctionality, exchange capacity, and thermal stability.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 683-692 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Influence of hydrofuramide and ethanolamines on efficient vulcanization (EV), semi-EV, and conventional sulfur vulcanization accelerated by tetramethyl thiuram disulfide is reported. In the case of thiuram vulcanization, the amines increase the cure rate but reduce the crosslink density. The interaction of tetramethyl thiuram disulfide with amines has been studied. The amines interact with thiuram disulfide (TMTD) giving rise to the formation of gaseous products. Thermogravimetric analysis shows weight loss of about 50% in case of TMTD-ethanolamine system and 25% in case of TMTD-hydrofuramide system. Gas chromatographic studies of the gaseous products indicate that it consists mainly of H2S. The other constituents in the gaseous product are CO2 and a thiol. A possible reaction based on these observations to account for decrease in crosslink density in thiuram vulcanization caused by amines is reported.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 179 (1978), S. 1209-1217 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Studies on the relative efficiencies of 3d-transition metal oxides as catalysts for the polymerization of vinyl ethers revealed that V2O5 is the most efficient catalyst. Some kinetic studies with the system isobutyl vinyl ether/V2O5/benzene were carried out at ambient temperature. It was found that the rate is second order in isobutyl vinyl ether (IBVE) concentration (0,25 to 2,0mol.1-1) and the inhibition of the polymerization by pyridine suggests a cationic mechanism. Rp increases by the use of benzaldehyde along with V2O5, whereas water (3.10-3mol.1-1) seems to have no effect on Rp. Over the temperature range of 15 to 60°C, Rp as well as [η] attain a maximum value at about 32°C. [η] is unaffected by varying the amounts of oxides, whereas it increases with increasing IBVE concentration. No stereoregularity in the product polymer was observed by using V2O5 alone or in combination with modifiers such as benzaldehyde or carbon disulfide. The kinetics are interpreted in terms of the Hinshelwood-Langmuire mechanism assuming a single point adsorption.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 68 (1935), S. 427-428 
    ISSN: 0365-9631
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
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