ISSN:
0721-3115
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The kinetics of the reaction of di- and triethylamine with 1,8-dimethyl-2,4,5-trinitronaphthalene (245 TND) have been studied in dimethylsulfoxide and dimethylsulfoxide-methanol solvent systems and comparison made with data for corresponding reactions involving 1,5-dimethyl-2,4,8-trinitronaphthalene (248 TND). Analysis of the results shows that the formation of a benzyl-type anion is more facile with 245 TND than with 248 TND. Thus, the former compound has the greater potential for base-induced coupling to give thermally stable explosive material.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prep.19840090404
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