ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Silicon Compounds with Strong Intramolecular Steric Interactions, 13. Restricted Rotations in Tri-tert-butylsilanesSeveral tri-tert-butylhalosilanes and tri-tert-butyl(dihalomethyl)silanes were studied by dynamic NMR spectroscopy. The rotation barriers were determined by line shape analysis of the NMR spectra at various temperatures. A model for the rotation pathway was developed and compared with the static and dynamic stereochemistry of tri-tert-butylisopropylsilane as obtained by empirical force field calculations.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19821151021
Permalink