ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Complexes of formulae Ni(HRS)2X2 (X=Cl or Br), M(HRS)2Y2 (M=Ni or Pd; Y=NO2 or C1O4), Pd(HRS)X2 (X=Cl, Br or I), Pt(HRS)X2 (X=Cl or Br), Pt(HRS)2(ClO4)2 and M(RS)2 (M=Pd or Pt) where HRS and RS denote 1-methyl-4-mercaptopiperidine in the zwitterionic or in the thiolato form, respectively, have been prepared and characterized. In all the complexes the ligands are coordinated exclusively through sulphur. Polymeric structures consisting of square-planar geometry with sulphur-bridged metal atoms are proposed in each case.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618554
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