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  • 1980-1984  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 116 (1983), S. 610-617 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Diazadiphosphetidines, VI. Synthesis of Diazaphosphetidines, Diazadiphosphetidines, and ThiadiazaphosphetidinesA method of synthesis for the title compounds is reported. The syntheses of 2-(diethylamino)-1,3-dimethyl-1,3,2-diazaphosphetidin-4-one (1), 4-(diethylamino)-1,2,3-triphenyl-1,3,2,4-diazadiphosphetidine 2-oxide (3), and 3-(diethylamino)-2,4-diphenyl-1,2,4,3-thiadiazaphosphetidine 1,1-dioxide (4) are described. The compounds are characterized by their spectra and by some of their reactions.
    Notes: Eine Synthesemethode für die Titelverbindungen wird mitgeteilt. Die Synthesen von 2-(Diethyl-amino)-1,3-dimethyl-1,3,2-diazaphosphetidin-4-on (1), 4-(Diethylamino)-1,2,3-triphenyl-1,3,2,4-diazadiphosphetidin-2-oxid (3) und 3-(Diethylamino)-2,4-diphenyl-1,2,4,3-thiadiazaphosphetidin-1,1-dioxid (4) werden beschrieben. Die Verbindungen werden spektroskopisch sowie durch einige ihrer Reaktionen charakterisiert.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1980 (1980), S. 1651-1658 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and NMR Spectra of Diazadiphosphetidines, II1,3,2λ5,4λ5-Diazadiphosphetidines are synthesized from PCl5 and aniline derivatives. They are partially or fully dissociated in solution to give substituted (phenylimido)phosphoric trichlorides. The dependence of the dissociation on the solvent, the temperature, and the concentration has been investigated. The reaction products of anilines and C6H5PCl4 or (C6H5)2PCl3 are exclusively monomers, i. e. they are substituted phenyl(phenylimido)phosphonic dichlorides 3 or diphenyl-(phenylimido)phosphinic chlorides 4, respectively.
    Notes: 1,3,2λ5,4λ5-Diazadiphosphetidine 1 werden aus PCl5 und Anilinderivaten synthetisiert. Sie liegen in Lösung teilweise oder ganz dissoziiert als substituierte (Phenylimido)phosphorsäuretrichloride 2 vor. Es wurde die Abhängigkeit der Dissoziation vom Lösungsmittel, der Temperatur und der Konzentration untersucht. Die Reaktionsprodukte aus Anilinen und C6H5PCl4 oder (C6H5)2PCl3 sind ausschließlich monomer, d. h. es handelt sich um substituierte Phenyl(phenylimido)phosphonsäuredichloride 3 bzw. Diphenyl(phenylimido)phosphinsäurechloride 4.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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