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  • Polymer and Materials Science  (3)
  • 1980-1984  (3)
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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4477-4491 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Alkaline hydrolysis causes pitting of the surface of polyester (PET) fibers and films and improves their wettability, as indicated by contact angle measurements. The enhanced wettability is due to an increase in either the number or the accessibility of polymer hydrophilic groups to water and/or an increase in the roughness of sample surfaces. The increase of void space in the PET yarn and fabric structure, induced by treatment in aqueous NaOH together with the increased wettability of the fibers, was effective in improving the moisture transport properties of the materials. The NaOH-treated PET fabrics transported the water further than isolated corresponding yarns, possibly because, in the fabrics, the spaces between the yarns acted as an additional reservoir that permitted further wicking to occur. It is apparent from immersion and equilibrium wicking capacity tests that a hydrophilic topical finish, as well as a change in the yarn/fabric structure and the hydrophilicity of their surfaces can increase the water holding capacity of PET fabric. The moisture regain and water retention values of the samples were determined, and it was found that such tests are not sufficiently sensitive to distinguish between the hydrophilicity of nontreated PET fabrics and that of PET fabrics modified either by application of a topical finish or by NaOH treatment.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 2465-2466 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 2181-2194 
    ISSN: 0006-3525
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: At sufficiently high ionic strength, long-range electrostatic interactions in a polyelectrolyte such as poly(L-glutamic acid) might be adequately approximated in matrix calculations by use of statistical weights representing second-order interactions. The validity of this assumption has been investigated making use of experimental observations (CD spectra and titration curves) for poly(L-glutamic acid) as a function of temperature in 0.1-0.5M sodium chloride. Theoretical analysis, using a statistical weight matrix proposed by Warashina and Ikegami, is based on the Zimm-Rice theory. Implementation differs from that of Warashina and Ikegami in one respect. Refinement of the initial estimates is achieved using a form of the configuration partition function which does not assume diagonalization of the statistical weight matrix. This difference is of no consequence for the values of σ and s, but it does produce somewhat different values for the statistical weights used to represent the electrostatic interactions. The method used to treat electrostatic interactions in poly(L-glutamic acid) in 0.1M sodium chloride can be viewed as successful in that it properly reproduces the helix-coil transition and titration curves in this solvent and the molecular-weight dependence of the titration curves yields values for s in harmony with those obtained using a treatment which is independent of model, and gives a reasonable ionic-strength dependence for the electrostatic parameters. Furthermore, the model can account for measured helix-coil transitions and titration curves in homopolypeptides in which the side chain is  - (CH2)xNHCO(CH2)yCOOH. The model, however, is not exact. It does not properly account for the molecular-weight dependence of the helical content for polymers of low degree of polymerization.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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