ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In recent publications we have described a novel method of analysis for high-resolution NMR spectra of compounds in isotropic solution which differs from conventional procedures in that it exploits the full information content of a spectrum and does not require assignments of energy levels or transitions. We now present a further development of this technique which also makes it applicable to the NMR spectra of molecules partially oriented in liquid crystal solvents. Illustrative applications are reported for the nematic phase spectra of allyl fluoride, allyl chloride and allyl bromide. The results are discussed in terms of various theoretical models of the interplay between the internal and overall rotations of the conformationally mobile solutes.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270140315
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