ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The preparation of fourteen complexes of the type [Pd(C6F5)L2(CNR)]ClO4 (L2=2PR′3, bipy, tmen or diphos; R=But, Cy orp-Tol) is described. Their reactivity with alcohols or amines is much lower than that of similar haloderivatives. Only the complexes with L2=chelating ligand react with YH to form the corresponding carbene complexes [Pd(C6F5)(chelate){C(NHTol)Y}]ClO4 (YH=p-TolNH2, BzNH2, ButNH2, MeOH or EtOH), which can be deprotonated with KOH in alcohol, rendering the first imidoylorganopalladium complexes [Pd(C6F5){C(=NTol)Y}(bipy)].
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618788
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