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  • 1985-1989  (2)
  • 1980-1984  (2)
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  • 1
    Publication Date: 1984-01-01
    Print ISSN: 0043-1656
    Electronic ISSN: 1477-8696
    Topics: Geosciences
    Published by Wiley
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  • 2
    Publication Date: 2016-06-07
    Description: TRW is in the process of data accumulation that strongly indicates that incorporation of the perfluorsisopropylidene linkage in molecular structures other than those employed in DU Pont's NR-150B polyimides likewise yield polymers demonstrating extremely high thermo-oxidative stability. Polyimide synthetic and characterization studies conducted to date on new polymers incorporating the perfluoroisopropylidene linkage are presented and discussed.
    Keywords: COMPOSITE MATERIALS
    Type: NASA. Lewis Research Center High Temp. Polymer Matrix Composites; p 271-285
    Format: application/pdf
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  • 3
    Publication Date: 2019-06-28
    Description: Partially fluorinated polyimides were prepared and molded in the form of discs and pins for test as potential apex seal materials for advanced rotary combustion engines. The polyimides were formulated from the diamine 2,2-bis 4-(4-aminophenoxy)phenyl hexafluoropropane (4-BDAF) and the dianhydrides of pyromellitic acid (PMDA) and benzophenonetetracarboxylic acid (BTDA). Tribological testing was performed at sliding speeds of 0.31 to 11.6 m/s and at temperatures of from 298K to 573K. It is shown that the carbon fiber filled polyimides, particularly the 80/20 compositions, have an excellent balance of wear/friction at 573K. The unfilled, 80/20 and 60/40 compositions indicate an unusual combination of high friction and low wear which may be advantageous in such applications as brakes and traction drives.
    Keywords: MECHANICAL ENGINEERING
    Type: NASA-CR-174706 , NAS 1.26:174706 , TRW-38603-6009-UT-00
    Format: application/pdf
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  • 4
    Publication Date: 2019-06-28
    Description: A study was performed with the objective of developing matrix resins that exhibit improved thermo-oxidative stability over state-of-the-art high temperature resins for use at temperatures up to 644 K (700 F) and air pressures up to 0.7 MPa (100 psia). The work was based upon a TRW discovered family of polyimides currently licensed to and marketed by Ethyl Corporation as EYMYD(R) resins. The approach investigated to provide improved thermo-oxidative properties was to use halogenated derivatives of the diamine, 2, 2-bis (4-(4-aminophenoxy)phenyl) hexafluoropropane (4-BDAF). Polyimide neat resins and Celion(R) 12,000 composites prepared from fluorine substituted 4-BDAF demonstrated unexpectedly lower glass transition temperatures (Tg) and thermo-oxidative stabilities than the baseline 4-BDAF/PMDA polymer.
    Keywords: NONMETALLIC MATERIALS
    Type: NASA-CR-180826 , NAS 1.26:180826
    Format: application/pdf
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