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  • 1
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3363-3371 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The displacement reaction H↘+BrH'(ad)→HBr(g)+H' resulting from the photoinduced interaction of adsorbed HBr molecules on a LiF(001) substrate has been modeled by a quasiclassical trajectory (QCT) calculation. This process constitutes "surface-aligned photoreaction'' (PRXN) in which atomic H↘ photoejected from HBr(ad) approaches an adjacent HBr(ad) with a restricted range of impact parameters b in either linear or bent (90°) configurations. The surface alignment (whether linear or bent) was found to eliminate the reaction pathway to yield H2 product, of major importance in the gas. Product HBr energy and angular distributions, as well as excitation functions Pr(ET), were obtained for each geometry at initial relative translational energies ET spanning 8–40 kcal mol−1. These distribution functions were compared to the gas. For both PRXN variants, linear or bent, reaction occurred with high probability, Pr(ET) rising sharply in each case from threshold to unity within a narrow range of ET. By contrast, Pr(ET) for the gas was broader and smaller. Product (HBr) vibrational excitation for PRXN exceeded that for gas-phase reaction; linear PRXN showed the greatest enhancement. Product rotational distributions were substantially narrower than for the gas-phase reaction, with P(J') for bent PRXN exhibiting bimodality attributable to the occurrence of reaction with either positive or negative impact parameters. The computed HBr angular distributions from PRXN were markedly narrower than for the gas-phase reaction, and were specific to the reagent configuration (linear or bent). The existence of a reference plane in PRXN (the crystal surface) governing the plane of reaction, has the consequence that product angular distributions with respect to each polar angle Pr(θ's) and Pr(φs), embody information concerning the reaction dynamics. It is evident that PRXN by restricting reagent parameters renders product attributes more informative.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Biophysics and Biomolecular Structure 17 (1988), S. 71-97 
    ISSN: 0084-6589
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Biology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Weed research 27 (1987), S. 0 
    ISSN: 1365-3180
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Seeds of Poa trivialis L. were collected from one grassland and two arable habitats. Seeds from the grassland population were less dormant than the arable populations. Distal (upper) seeds were consistently more dormant than proximal (basal) seeds. Dry storage at 4°C and 15°C for 4 weeks after shedding resulted in a slightly greater loss of dormancy than storage at 23°C. Germination was enhanced by subjecting seeds stored at 15°C to repeated hydration and dehydration cycles. Germination of P. trivialis seeds was density-dependent. Germination of distal seeds was particularly impaired at high densities. The ecological implications of these results are discussed in relation to seed survival strategies.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Weed research 27 (1987), S. 0 
    ISSN: 1365-3180
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Weeds in a total of 450 fields of winter oilseed rape in nine areas of central southern England were surveyed, just prior to harvest during summer 1985, to identify those that had survived herbicide treatment or had not been sprayed and, thus, were capable of re-infestation or contamination of the harvested crop. Sixty-two species were identified; their levels of infestation were scored and distribution within the field noted. The most frequent species was Galium aparine, which occurred in 57% of fields. Mayweeds (Tripleurospermum inodorum, Matricaria recutita and Anthemis cotula) occurred in 23% of fields and Papaver rhoeas in 21%. All other species occurred in less than 20% of fields, the most prevalent being Sonchus asper(18%). Grassweeds were relatively infrequent, reflecting the widespread use of effective graminicides; the most prevalent was Arena spp., found in 9% of fields. Although most species were distributed throughout the field, Geranium dissection (13%) and Sisymbrium officinale (7%) were virtually confined to field margins (extending 1 m into the crop) and headlands (10m into the crop), respectively. Several species exhibited a well-defined regional distribution; Silene alba was virtually restricted to the most southern counties surveyed, whilst Papaver rhoeas and Viola arvensis were conspicuously absent from the eastern area.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1095-8649
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: The use of Bacille Calmette Guerin (BCG) and the saponin Quil-A as a means of potentiating the immune response elicited by immersion vaccination of Salmo gairdneri with a commercial enteric redmouth (ERM) vaccine was investigated. The bactericidal activity of trout serum to Yersinia ruckeri, the causative agent of ERM, was enhanced by vaccination, although non-specific factors appear to serve an important defensive function. Whilst the use of BCG and Quil-A produced no conclusive improvement of the immune response, as determined by bacterial agglutination and serum bactericidal activity, some enhancement of in vivo bacterial clearance was apparent. Differences were observed in the susceptibility to trout serum of the three strains of Y. ruckeri tested.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 332 (1988), S. 393-393 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] CHEMISTS have been trying for many years to produce self-assembling monolayers, similar to those of natural membranes but deposited on electrodes to give a selective response to solutes. I. Rubinstein et al. report on page 426 of this issue that they have achieved this objective by designing a ...
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 331 (1988), S. 26-26 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] EVERY now and then one comes across something different and what a blessing it is. This book is overtly about silicon, its chemistry and physics, and yet it is about something quite other. It is almost an autobiography. Professor Rochow wants to educate us in a gentle way about silicones and ...
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 324 (1986), S. 565-567 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Figure 1 illustrates the general reaction scheme adopted in our work. Unilamellar phospholipid vesicles with diameters of 300 A were prepared from phosphatidylcholine (17 mM) sus pensions at 4 C in the presence of Fe(ii) and/or Fe(iii) solutions. Three preparative routes were investigated: ...
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  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 342 (1989), S. 135-136 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] LINUS Pauling is a tragic hero of the scientific age. His work on chemical bonding and secondary protein structure, amongst other contributions, means he ranks as a very great scientist. His coupling of the scientific analysis of nuclear reactions with pleas for political wisdom in the testing of ...
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