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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 11-18 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Fully electromagnetic particle-in-cell simulations of Applied-B ion diodes have been performed using the magic code. These calculations indicate that Applied-B diodes can be nearly 100% efficient. Furthermore, the simulations exhibit an impedance relaxation phenomenon due to the buildup of electron space charge near the anode which causes a time-dependent enhancement of the ion emission above the Child–Langmuir value. This phenomenon may at least partially explain the rapidly decreasing impedance that has been observed in Applied-B ion diode experiments. The results of our numerical simulations will be compared to experimental data on Applied-B ion diodes and to analytic theories of their operation.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A series of experiments was performed with an Applied-B ion diode on the Particle Beam Fusion Accelerator-I, with peak voltage, current, and power of approximately 1.8 MV, 6 MA, and 6 TW, respectively. The purpose of these experiments was to explore issues of scaling of Applied-B diode operation from the sub-TW level on single module accelerators to the multi-TW level on a low impedance, self-magnetically insulated, multimodule accelerator. This is an essential step in the development of the 100-TW level light ion beam driver required for inertial confinement fusion. The accelerator and the diode are viewed as a whole because the power pulse delivered by the 36 imperfectly synchronized magnetically insulated transmission lines to the single diode affects module addition, diode operation, and ion beam focusability. We studied electrical coupling between the accelerator and the diode, power flow symmetry, the ionic composition of the beam, and the focusability of the proton component of the beam. Scaling of the diode impedance behavior and beam quality with electrical drive power is obtained from comparison with lower-power experiments.The diode impedance lifetime was about 10 ns, several times shorter than for lower-power experiments. Azimuthal and top-to-bottom variations of the diode and ion currents were found to be approximately ±10%, compared with an estimated requirement of 5%–7% uniformity to avoid focal blurring by self-magnetic field effects. The ion production efficiency was 80%–90%. However, only 50%±10% of the ion current was carried by protons; the balance was carried by multiply charged carbon and oxygen ions. Activation measurements showed a proton beam energy of approximately 50 kJ. A gas cell filled with 5 Torr of argon was used for beam transport. The macroscopic divergence was 15±10 mrad and the microscopic divergence was 20±15 mrad, values that are similar to those from lower-power experiments. A model of beam focusing is formulated that predicts the proton charge focused onto 0.47-cm radius lithium targets, taking into account beam purity, magnetic bending, small-angle multiple scattering, and intrinsic divergence. The model results and activation measurements of the number of protons focused onto targets agree, and indicate that the spatially averaged (over about 3 cm2) peak focal power was about 0.5 TW/cm.2 The most important limitations on power concentration were found to be the low proton content of the beam, the short impedance lifetime of the diode, and the asymmetric current feed of the accelerator. The short impedance lifetime limited the power coupled to the diode, and caused the voltage at peak ion power to be low, which exacerbates the small-angle scattering problem. The asymmetric feed caused focal blurring through nonuniform self-magnetic bending. At least partly because of the experience gained with low impedance beams during these experiments, the next generation accelerator, the 100-TW Particle Beam Fusion Accelerator-II, has been configured to produce a 25–30-MV Li+ beam rather than a 5-MV proton beam. off
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 4970-4977 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present the design of the high-voltage (30 MV) Applied-B ion diode that is now being tested on the PBFA-II accelerator at Sandia National Laboratories. This diode design is the first application of a new set of numerical design tools that have been developed over the past several years. Furthermore, this design represents significant departures from previous designs due to much higher voltage and the use of a nonprotonic ion, Li+. The higher voltage increases the magnetic field strength required to insulate the diode from 1 to 2 T of previous diodes to 3–7 T. This represents a very large increase in the magnetic field energy and the magnetic forces exerted on the field-coil structures. Our new design incorporates changes in the field-coil locations to significantly reduce the field energy and the forces on the field-coil structures. The use of nonprotonic ions introduces a new complication in that these ions will be stripped when they penetrate material, i.e., the gas cell membrane. The importance of current neutralization, charge-exchange reactions, and the conservation of canonical angular momentum are discussed in the context of designing light ion diodes suitable as drivers for inertial confinement fusion. We have simulated the performance of this diode design using the electromagnetic particle-in-cell code, magic. We find that the most sensitive point in the power flow is the transition from the self-magnetically insulated transmission line to the applied field region of the diode.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 324 (1986), S. 217-218 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of New Unsymmetrically Substituted N-(2-Aminophenyl)-azomethines of β-Ketoaldehydes via Template Condensation with Nickel(II) as Potential Precursors of Unsymmetrically Substituted Macrocyclic ComplexesThe synthesis of new unsymmetrically substituted nickel(II) complexes of type 4 is described. These complexes arises via template condensation of the unsymmetrically substituted tridentate amino-azomethines 3, whereas only the amino group of the less reactive and the carbonyl group of the more reactive aminoazomethine react with each other. Diamagnetic square-planar nickel(II) complexes with a [N3O] donor set and an uncoordinated amino group are formed. The complexes are precursors of carbonyl-substituted macrocyclic chelates. Further condensations of the amino group with e. g. dialdehydes or diketons are possible. All the new complexes are characterized by visible and 1H and 13C n.m.r. spectra as well. The influence of several peripheral substituents on the distribution of the electron density of the ligand is investigated. Strong O…H bonds forms a 6-membered ring between the uncoordinated amino group, the coordinated carbonyl group and the substituents at the R3 position.
    Notes: Die Synthese neuer unsymmetrisch substituierter Nickel(II)-Komplexe des Typs 4 wird beschrieben. Die Komplexe entstehen durch Template-Kondensation der unterschiedlich substituierten dreizähnigen Aminoazomethine 3, wobei nur die Aminogruppe des weniger reaktiven und die Carbonylgruppe des reaktiveren Aminoazomethins miteinander reagieren. Es entstehen diamagnetische planare Nickel(II)-Komplexe mit [N3O]-Koordination und einer freien Aminogruppe. Die Komplexe stellen Vorstufen für carbonylsubstituierte makrocyclische Chelate dar. Die freie Aminogruppe ist weiteren Kondensationsreaktionen, z. B. mit Dialdehyden oder Diketonen, zugänglich. Alle neuen Komplexe werden durch sichtbare sowie 1H- und 13C-NMR-Spektren ausführlich charakterisiert. Der Einfluß der verschiedenen peripheren Substituenten auf die Verteilung der Elektronendichte im Liganden wird untersucht. Zwischen der freien Aminogruppe des Liganden, der koordinierten Carbonylgruppe und dem Substituenten R3 bildet sich über starke H-Brücken ein Sechsring aus.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Bioluminescence and Chemiluminescence 4 (1989), S. 436-445 
    ISSN: 0884-3996
    Keywords: Bioluminescence ; chemiluminescence ; lipid metabolism ; LDL oxidation ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Using bioluminescence assays for glycerol, free fatty acids, β-hydroxybutyrate and lactate, we were able to perform complex studies of human energy and lipid metabolism both in serum samples in vivo and in isolated fat cells in vitro. These studies would have been impossible without reliable, specific and highly sensitive luminescence methods. Oxidatively modified low density lipoprotein (LDL) has been implicated in the pathogenesis of atherosclerosis. Adaptation of a chemiluminescence assay for lipid hydroperoxides to LDL isolated by specific precipitation from serum makes it possible to measure LDL oxidation in vivo. Cell dependent chemiluminescence was used to investigate whether receptor mediated endocytosis of LDL by macrophages leads to oxygen radical production in these cells. No activation of the membrane NAD(P)H oxidase was observed.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Structure Reactivity Correlations on Coordinatively Unsaturated Metal Chelate Complexes. XI. Effect of the Central Atom and the Ligands on the Mass Spectrometric Fragmentation of Chelate Complexes with Macrocyclic and Open Chain Schiff Base LigandsThe influence of the central atom on the mass spectrometric fragmentation of the compounds 1-5 is compared. Whereas the ligands (Mt = 2H) show a strong fragmentation with a farreaching cleavage, the metal complexes with exception of Cu-4 and Cu-5 show always the molecular ion signal as the base peak. The main fragmentions [M-C2H5O]⊕, [M-2(C2H5O)]2⊕, [M-C2H4]⊕., and [M-C2H4CO2]⊕. may be related to the ‘cyclidene’ structures 6-7, the carboxylic acid 8, and its decarboxylation product 9. In the case of the copper chelates 1-4 the fragment [M-C2H6O].⊕/2⊕ with one or two positive charges is dominating over the peak [M-C2H5O]⊕. This may be due to the abstraction of one H from an ethylene (type 1, 2, 4) or a methyl (type 3) group with concomitant reduction to Cu(I) (10) or oxidation to Cu(III) (11).
    Additional Material: 7 Tab.
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  • 8
    Publication Date: 1986-01-01
    Print ISSN: 0016-1152
    Topics: Chemistry and Pharmacology
    Published by Springer
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  • 9
    Publication Date: 1985-08-01
    Print ISSN: 0556-2791
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
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  • 10
    Publication Date: 1986-01-01
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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