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  • 1985-1989  (1)
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    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1927-1935 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Formation of Oxetanes via Photo-sensitized Oxidation of EnaminesPhotooxidations of the enamines 1 and 5 in toluene give rise to the formation of the usual reaction products. In methanol, however, the oxetanes 8 and 13, respectively, are isolated as the main photooxidation products. Both the mechanism of their formation as well as some reactions of 8 and 13 are discussed. Oxidation of 13 with m-chloroperbenzoic acid produces the aldehyde 15 via a multi-step reaction.
    Notes: Die Photooxidation der Enamine 1 bzw. 5 in Toluol liefert die erwarteten Reaktionsprodukte. In Methanol entstehen dagegen die Oxetane 8 bzw. 13 als Hauptprodukt der Photooxidation. Die Reaktionen dieser Verbindungen werden beschrieben. Die Oxidation von 13 mit m-Chlorperbenzoesäure führt über einen mehrstufigen einheitlichen Reaktionsablauf zum Aldehyd 15. Der Bildungsmechanismus der Oxetane 8 und 13 wird diskutiert.
    Type of Medium: Electronic Resource
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