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  • 1985-1989  (2)
Collection
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 27 (1989), S. 655-671 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Monte Carlo simulations based on the rotational isomeric model are used to investigate the influence of a neutral surface on the structural and thermodynamic descriptors of polymethylene chains on and in the vicinity of the surface. For large chains, the results of the simulations are replicated by a properly scaled distribution based on a random walk with absorbing barriers. Accordingly, the affects noted for the trial polymethylene system may be extended to other molecules.The perturbations in the geometry of the chain were confined to the components of the various descriptors perpendicular to the surface; the radial components were unaffected by the neutral surfaces. The perturbations induced by the neutral surfaces extend to chains whose origins were within about $\[ 10\left\langle {s_x \left( \infty \right)^2 } \right\rangle ^{1/2} \]$, where $\[ \left\langle {s_x \left( \infty \right)^2 } \right\rangle ^{1/2} \]$ is the perpendicular component of the mean square radius of gyration of an unperturbed chain.In contrast, the average bond conformation, the associated internal energy, and the variance of the internal energy distribution are unaffected by a neutral surface. The major thermodynamic effect is manifest through the entropy arising from the reductions in accessible chain configurations due to the neutral barrier.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 7 (1986), S. 455-462 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effects of tension on the absorbance of water at 60°C into neat and glass-bead-filled, cross-linked polyester are reported. Experimental apparatus and procedure to determine water uptake for these materials subjected to three tensile stresses in the range of 0 to 30 percent of the breaking stress of the neat dry polyester are described. It was found, for bead-filled samples, that a load of approximately 4.9 × 106 N/m2 caused the absorption level to increase by 30 percent over that of an unloaded sample. Tensile load was found to have no effect on the absorption characteristics of neat polyester. However, breaking stress was reduced to less than 15 percent of that in the dry neat material. Optical microscope examinations of damage at the fracture surfaces and at the sample cores indicate that the excess moisture uptake in bead-filled samples was not due to microcrack formation.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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