ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The complexes trans-[PtXY(2] (X = H or Me; Y = OMe, OCHO, CO2H, and BH4; 2 = 2,11-bis{bis[3-(trifluoromethyl)phenyl]phosphinomethyl}benzo[c]phenanthrene) were prepared, and their decompositions to trans[PtHX(2)] were studied. Some binuclear hydrido-bridged complexes, e.g.[(2)HPt(μ-H)PtH(2)]+, were also obtained. The preparation of complexes trans-[PtHX(28)2] (X = H or Me, 28 = bis[3-(trifluoromethyl)phenyl]benzylphosphine) is also reported. The X-ray crystal structure of trans-[PtHCl1)] (1 = 2,11-bis(diphenylphosphinomethyl)benzo[c]phenanthrene) was carried out.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19880710608
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