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  • 1
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    Regulation of inducible and tissue-specific gene expression (1987)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1987-06-05
    Description: Molecular genetics approaches have been used to identify and characterize cis-acting DNA sequences required for eukaryotic gene regulation. These sequences are modular in nature, consisting of arrays of short (10- to 12-base pair) recognition elements that interact with specific transcription factors. Some transcription factors have been extensively purified and the corresponding genes have been cloned, but the mechanisms by which they promote transcription are not yet understood. Positive and negative regulatory elements that function only in specific cell types or in response to extracellular inducers have been identified. A number of cases of inducible and tissue-specific gene expression involve the activation of preexisting transcription factors, rather than the synthesis of new proteins. This activation may involve covalent modification of the protein or an allosteric change in its structure. The modification of regulatory proteins may play a central role in the mechanisms of eukaryotic gene regulation.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Maniatis, T -- Goodbourn, S -- Fischer, J A -- New York, N.Y. -- Science. 1987 Jun 5;236(4806):1237-45.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3296191" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Enhancer Elements, Genetic ; Eukaryotic Cells ; Forecasting ; *Gene Expression Regulation ; Genes, Regulator ; Humans ; Models, Genetic ; Promoter Regions, Genetic ; Transcription Factors ; Viruses/genetics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 2
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    Sequence homology between certain viral proteins and proteins related to encephalomyelitis and neuritis (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-07-19
    Description: Post-infectious or post-vaccinal demyelinating encephalomyelitis and neuritis may be due to immunological cross-reactions evoked by specific viral antigenic determinants (epitopes) that are homologous to regions in the target myelins of the central and peripheral nervous systems. Such homologies have been found by computer searches in which decapeptides in two human myelin proteins were compared with proteins of viruses known to infect humans. These viruses include measles, Epstein-Barr, influenza A and B, and others that cause upper respiratory infections. Several regions identified in myelin basic protein and P2 protein can be related to experimental allergic encephalomyelitis or neuritis in laboratory animals.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Jahnke, U -- Fischer, E H -- Alvord, E C Jr -- AM07902/AM/NIADDK NIH HHS/ -- New York, N.Y. -- Science. 1985 Jul 19;229(4710):282-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2409602" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Base Sequence ; Chickens ; Encephalomyelitis/etiology/immunology/*metabolism ; Epitopes ; Guinea Pigs ; Haplorhini ; Humans ; Measles/metabolism ; Myelin Basic Protein/genetics ; Myelin P2 Protein ; Neuritis/etiology/immunology/*metabolism ; Rabbits ; Rats ; Rats, Inbred Lew ; Viral Proteins/*genetics ; Viral Vaccines/adverse effects/immunology
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 3
    Electronic Resource
    Electronic Resource
    Karpoxanthin und 6-Epikarpoxanthin (1985)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 68 (1985), S. 1704-1707 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Karpoxanthin and 6-EpikarpoxanthinA tetrahydroxy-β,β-carotene previously isolated in minute amounts from ripe hips of Rosa pomifera was now identified as (3S,5R,6R,3′R)-5,6-dihydro-β,β-carotene-3,5,6,3′-tetrol (2). Acid hydrolysis of (9Z)-antheraxanthin (3) gave 2 and its C(6)-epimer 4. Tetrol 2 is named karpoxanthin.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19850680626
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  • 4
    Electronic Resource
    Electronic Resource
    Das Carotinoidspektrum der Antheren und Petalen von Lilium tigrinum cv. ‘Red Night’ (1985)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 68 (1985), S. 1708-1715 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Carotenoids from Anthers and Petals of Lilium tigrinum cv. ‘Red Night’Amongst the 29 carotenoids separated and characterized by modern methods the following are worth mentioning: (9′Z)-, (9Z)-, (13′Z)- und (13Z)-capsanthins (20-23), the novel 6-epikarpoxanthin (= (3S,5R,6S,3′R)-5,6-dihydro-β,β-carotene-3,5,6,3′-tetrol; 25), karpoxanthin (= (3S,5R,6R,3′R)-5,6-dihydro-β,β-carotene-3,5,6,3′-tetrol; 28), and lilixanthin (= (3S,4S,3′S,5′R)-3,4,3′-trihydroxy-β,κ-carotene-6′-one; 26). The main carotenoids from the petals, in comparison with those of the anthers, represent a more advanced metabolic state.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19850680627
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  • 5
    Electronic Resource
    Electronic Resource
    Die toxischen und sedierend wirkenden Bufadienolide von Kalanchoedaigremontiana HAMETet PERR (1986)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 69 (1986), S. 359-367 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Toxic and Sedative Bufadienolides of Kalanchoe daigremontiana HAMET et PERR.From the toxic Crassulacee Kalanchoe daigremontiana five biosynthetically related bufadienolides have been isolated and structurally elucidated by X-ray and 1H- and 13C-NMR spectroscopy. The compounds were identified as bersaldegenin 1,3,5-orthoacetate (2), bersaldegenin 1-acetate (4), bersaldegenin 3-acetate (3), 1β,3β,5,11α,14-pentahydroxy-12,19-dioxo-5β,14β-bufa-20,22-dienolide 1,3,5-orthoacetate ( = daigremontianin; 1), and 3β-acetoxy-1β,5,14-trihydroxy-5β,14β-bufa-20,22-dienolide ( = daigredorigenin-3-acetate, 5). According to the pharmacological investigations, the two orthoacetates 1 and 2 comprise the positive inotropic, sedative, and toxic activity of the plant.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19860690215
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  • 6
    Electronic Resource
    Electronic Resource
    Die stereoisomeren Sinensiaxanthine und Sinensiachrome: Trennung und Bestimmung ihrer absoluten Konfiguration. 7. Mitteilung über Rosenfarbstoffe6. Mitteilung, s. [1]. (1988)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 71 (1988), S. 24-30 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Stereoisomeric Sinensiaxanthins and Sinensiachromes: Separation and Absolute ConfigurationThe so-called sinensiaxanthins and sinensiachromes, important apocarotenols from various fruits, have been separated into 2 and 4 stereoisomers, respectively, and their absolute configurations have been determined: (3S,5R,6S)-5,6-epoxy-5,6-dihydro-10′-apo-β-carotene-3,10′-diol (2), its (9Z)-stereoisomer 7, the (8R)- and (8S)-epimers of (3S, 5R)-5,8-epoxy-5,8-dihydro- 10′ -apo-β-carotene-3, 10′-diol (4 and 5), and their (9Z)-stereoisomers 3 and probably 6. Thus, sinensiaxanthins are cleavage products from (Z/E)-isomeric antheraxanthins or violaxanthins (scission at C(9′)-C(10′)) and sinensiachromes analogously from mutatoxanthins or auroxanthins.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19880710103
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  • 7
    Electronic Resource
    Electronic Resource
    Complexes of 3,3′-Oxybis[(diphenylphosphino)methylbenzene] with Ni(II), Pd(II), Pt(II), Rh(I), and Ag(I). How Important is Backbone Rigidity in the Formation of trans-Spanning Bidenatate Chelates?? (1987)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 70 (1987), S. 158-170 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The bidentate diphosphine ligand, 3,3′-oxybis[(dipenylphosphino)methylbenzene] (1) forms monomeric, trans-square-planar complexes MX2(1) (M = Ni, Pd, Pt; X = Cl-, Br- I-, and, in part, N3-, NCS-, CN-, NO3-) as well as Pt(H)Cl(1), Pt(H)Br(1), and RhCl(CO)(1). Polymeric species have been observed with substitutionally inert metal centres: trans-[PtCl2(1)]2 and cis-[PtCl2(1)]n (mean value of n ≈ 4-5) 31P-NMR, and selected IR and UV/VIS parameters are reported. Ligand 1 shows a marked preference for trans-spanning and monomeric chelate formation, despite its various degrees of freedom of internal rotation in the lignad backbone. The readily available ligand 1 as well as analogues with other donor atoms, therefore, appear useful in most potential applications of trans-spanning chelate ligands. The crystal structure of AgCl(1)·0.5 (CH3)2C=O·0.39 C6H12 (space group C2/c,a = 21.02 Å, b = 14.57 Å, c = 24.79 Å, β = 99.77°, V = 7531.4 Å3, Z = 8) confirms the presence of three-coordinate Ag(I), with a coordination intermediate between a trigonal-planar and a T-shaped geometry (P-Ag-P = 145.61(8)°).
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19870700120
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  • 8
    Electronic Resource
    Electronic Resource
    Isolierung von 10′-Apo-β-carotin-10′-ol und (3R)-10′-Apo-β-carotin-3,10′-diol (Galloxanthin) aus Rosenblüten. 5. Mitteilung über Rosenfarbstoffe1. bis 4. Mitt., s. [1-4]. (1987)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 70 (1987), S. 1988-1993 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Isolation of 10′-Apo-β-carotene-10′-ol and (3R)-10′-Apo-β-carotene-3,10′-diol (Galloxanthin) from Rose FlowersThe novel (all-E)-10′-apol-β-carotene-10′-ol (2) and (all-E,3R)-10′-apo-β-carotene-3,10′-diol (5) have been isolated from petals of one yellow species and various whitish or yellow blend varieties of rose cultivars. Each (all-E)-compound is accompanied by a (Z)-isomer, probably the (9Z)-isomer. Diol 5 proved to be identical with galloxanthin, an apo-10′-carotenol previously isolated from the retina of chicken.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19870700803
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  • 9
    Electronic Resource
    Electronic Resource
    Rosafluin, ein neues Diapocarotindiol aus Rosenblüten. 8. Mitteilung über Rosenfarbstoffe7. Mitteilung: [1]. (1988)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 71 (1988), S. 1491-1497 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Rosafluine, a Novel Diapocarotenediol from Rose PetalsA strongly fluorescent trace compound from rose petals was identified as the as yet unknown 10,10′-diapocarotene-10,10′-diol ( = 4,9-dimethyldodeca-2,4,6,8,10-pentaene-1,12-diol; 2).
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19880710613
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  • 10
    Electronic Resource
    Electronic Resource
    Konformation und Dynamik von [6]Paracyclophan-8,9-dicarbonsäure-dimethylester. Eine 1H- und 13C-NMR StudieHerrn Prof. Dr. Dr. h.c. mult. G. Wilke zum 60. Geburtstag gewidmet (1985)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 68 (1985), S. 801-812 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Conformation and Dynamics of Dimethyl [6]Paracyclophane-8,9-dicarboxylate. A 1H- and 13C-NMR StudyThe 1H- und 13C-NMR spectra of dimethyl [6]paracyclophane-8,9-dicarboxylate have been assigned and analyzed in the slow-exchange limit (-20°C) for the ring-inversion process of the methylene bridge using several 2D-NMR techniques. The vicinal 1H, 1H coupling constants of the methylene chain show a Karplus-type dependence on torsional angles. The observed values indicate that the solution conformation of 1 closely resembles that found in the crystal. No significant changes in the 1H-NMR shielding properties of the boat-shaped benzene ring were detected. The 13C chemical shifts of the methylene C-atoms can be explained without invoking ring current contributions, which are too small for unambiguous identification. A lineshape analysis for the AB⇌BA exchange system of the aromatic protons yielded ΔH≠ = 43.25 ± 0.72 kJ/mol, ΔS≠ = -51.27 ± 2.66 J/K mol, and ΔG≠(298) = 58.53 kJ/mol for the dynamic process corresponding to an inversion of the methylene bridge.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19850680330
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