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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1487-1495 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(4-vinylphenylacetate-co-maleic anhydride) was synthesized by free-radical initiation to yield a 1:1 copolymer over a 0.2-0.8 mole fraction range of monomer feed in maleic anhydride. Evidence of 1:1 charge transfer complex between 4-vinylphenylacetate and maleic anhydride was obtained in the UV region at 355 nm. The 13C NMR chemical shifts and 1H NMR integration data indicate that poly(4-vinylphenylacetate-co-maleic anhydride) has an alternating and stereoregular structure. The molecular weight of poly(4-vinylphenylacetate-co-maleic anhydride) was controlled by using specific solvents and initiator concentrations.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 28 (1986), S. 678-683 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Batch and continuous fermentations with Clostridium thermoaceticum (ATCC 39073) using automatic pH control were conducted. The value of μmax obtained from batch fermentation was about 0.14 h-1; acetate yield, which was both growth and non-growth associated, was about 2 mole of acetic acid/mole of glucose, compared with a theoretical maximum value of 3. This low yield, compared with literature data, may be explained by glucose loss through a combination of degradation routes. Continuous fermentation could be sustained for 1600 h or more without contamination problems. Continuous fermentation at high dilution rates indicates that μmax may be well above 0.17 h-1 when fresh feed medium is used. Acetate yields in continuous fermentation were about 77% of theoretical or 2.3 mole of acetic acid/mole of glucose.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 3 (1989), S. 459-468 
    ISSN: 0268-2605
    Keywords: Substituted triptycenes ; arsenictriptycenes ; antimony-triptycenes ; phosphorustriptycenes ; bismuth-triptycenes ; mass spectra ; NMR ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass and NMR spectral data are presented for a number of dodecafluoro-1,6-disubstituted triptycenes. The epoxide OAs2(C6F4)2 can be made by heating together arsenic (As), arsenic(III) oxide (As2O3) and 1,2-di-iodotetrafluorobenzene (1,2-I2C6F4) in a sealed tube. The molecular structure of As2(C6F4)3 has been confirmed by X-ray crystallography.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Malachite green hydroxide and tetramethyl-p-phenylenediamine from complete films on solutions in hydroxypropionitrile and the He(I) photoelectron spectra of these liquid films are presented. The film of malachite green is shown to be in the covalent form although the ionic form predominates in solution.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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