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  • Wiley-Blackwell  (4,081)
  • 1985-1989  (4,081)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 26 (1988), S. 1271-1286 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Random copolymers of ethylene with 1-butene, 1-octene, and 1-octadecene have been prepared using a homogeneous vanadium-based catalyst system. Comonomer contents determined by 13C-NMR analysis of polymer solutions are in the range 1-10 mol%. Crystallinities were estimated by means of density measurements, x-ray diffraction, differential scanning calorimetry, laser Raman spectroscopy, and CPMAS 13C-NMR spectroscopy. The results are compared with those obtained for heterogeneous copolymers of ethylene containing 1-4 mol% 1-butene. As the comonomer content is increased, the crystallinity decreases. The dimension perpendicular to the 110 plane in orthorhombic crystallites decreases linearly with crystallinity. This decrease in crystallite size is accompanied by an increase in the size of the orthorhombic unit cell. For copolymers containing large amounts of 1-octene and 1-octadecene, a second crystalline form appears. Differences in estimates of crystallinity are discussed in terms of looser packing in highly branched copolymers and the extent to which the second crystalline form participates in the phase structure.
    Additional Material: 6 Ill.
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  • 2
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method for the quantitative determination of chlorpromazine and five of its major metabolites in a single sample of biological fluid in the ng/ml range has been developed utilizing gas chromatography/mass spectrometry with selected ion recording. The assay is highly specific and quantification is accomplished by an inverse stable isotope dilution technique, using deuterium-labeled variants of the compounds as internal standards. In this way the concentrations of chlorpromazine and five of its major metabolites (the sulfoxide, the N-oxide, the monodemethylated, the didemethylated, and the 7-hydroxylated compounds) can be determined in biological fluids. Levels in humans have been measured both in plasma and in red blood cells and are compared to those found in related in vitro studies.
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 480-487 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The facilitated transport of CO2 through ion exchange membranes containing organic amine counterions was studied. Steady state CO2 fluxes were measured from pure gas streams and mixtures with CH4. Facilitation factors for CO2 up to 26.7 were calculated from transport data. Transport measurements were binary mixtures of CO2 and CH4 yielded ratios of CO2 flux to CH4 flux ranging from 29.0 to 264. Conversion of flux ratios to permeabilities yielded separation factors up to 551 for CO2 over CH4, which are compared to literature data for polymeric membranes. The transport data support a mobile, reactive-carrier facilitated transport mechanism with a carbamate zwitterion complex. Effective diffusivities for CO2 and the carrier-gas complex were determined from transport data. A reaction equilibrium model predicted facilitation factors that were in very good agreement with experimental values. Potential applications are also discussed.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 131 (1985), S. 145-155 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The application of electron irradiated polypropylene granulate as a nucleating agent in extrusion has recently been suggested. This article discusses the chemical characterisation of such an electron treated granulate. Since the irradiation is carried out under atmospheric conditions, the relationship between decomposition, crosslinking and oxidation products has been determined. Oxidation is confined principally to the outermost molecular layers and leads to the formation of carbonyl groups via peroxide intermediates. As well as specific group tests, ESCA has been used to measure the degree of oxidation and for indirect determination of vinyl groups after bromination.
    Notes: In jüngster Zeit wird der Einsatz von elektronen-bestrahltem Polypropylengranulat als Nukleierungsmittel bei der Extrusion vorgeschlagen. Die vorliegende Arbeit beschäftigt sich mit der chemischen Charakterisierung der elektronen-bestrahlten Granulate. Da die Bestrahlung unter atmosphärischen Bedingungen stattfindet, werden nicht nur der Zusammenhang von Abbau und Vernetzung, sondern auch Oxidationsprodukte bestimmt. Die oxidative Schädigung findet hauptsächlich in den oberen Moleküllagen statt und führt über peroxidische Zwischenprodukte zur Entstehung von Carbonylgruppen. Neben für funktionelle Gruppen spezifischen Nachweismethoden wird die oberflächen-spezifische ESCA-Methode zur Erfassung des Oxidationsgrades und zur indirekten Vinylgruppenbestimmung nach der Bromierung eingesetzt.
    Additional Material: 1 Ill.
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  • 5
    ISSN: 0268-2605
    Keywords: Mercury bioaccumulation ; crayfish ; water ; food ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An in situ caged crayfish experiment was conducted in the Wabigoon River System, Ontario, Canada to determine the relative importance of food and water pathways for mercury accumulation in crayfish. Two groups of 160 crayfish were suspended in the water column; one at an ucontaminated site, the other at a location with highly elevated total mercury and methylmercury levels in water. Crayfish at each site were divided into two groups. Crayfish were fed either sucker flesh obtained from an uncontaminated lake (low mercury diet) or walleye flesh from contaminated Clay Lake, Ontario, Canada (high mercury diet). After 10 weeks crayfish at both sites fed the high mercury diet had over 20 times mercury accumulation compared to crayfish on the low mercury diet. There was no statistical effects due to sharply elevated water concentrations of total and methylmercury on mercury bodyburdens. This indicated that food was the dominant pathway for mercury accumulation in crayfish.
    Additional Material: 2 Ill.
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  • 6
    ISSN: 0192-253X
    Keywords: tubulin genes ; microtubules ; Arabidopsis thaliana ; Life and Medical Sciences ; Genetics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Notes: Microtubules are important components of the cytoskeleton of plant cells and play key roles in plant growth and morphogenesis. Recent molecular studies have begun to elucidate the structure and expression of plant genes coding for the major components of microtubules, α- and β-tubulin. Tubulin amino acid sequences deduced from the DNA sequences of eight higher plant tubulin genes are 79-87% homologous with constitutively expressed mammalian tubulins. The genome of the model plant system Arabidopsis thaliana contains four dispersed α-tubulin sequences and at least seven β-tubulin sequences, only two of which appear to be linked. Of the five A. thaliana genes whose expression has been analyzed, the transcripts of one α-tubulin and one β-tubulin gene are constitutively expressed in roots, leaves, and flowers. A second α-tubulin gene is expressed predominately in flowers; the transcripts of the second and third β-tubulin genes are found predominately in leaves or in roots, respectively.
    Additional Material: 7 Ill.
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  • 7
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The supermolecular structures of polyethylene filaments prepared by crystallization from solution in extensional flow at different crystallization temperatures as well as of annealed and zone-drawn samples have been characterized by means of X-ray diffraction methods. The lattice distortions in the crystallites of such samples are quantitatively determined for the first time. The results show that a direct correlation between the crystallite dimensions and the amount of lattice distortions on the one hand and the axial Young's modulus on the other hand can be excluded. Based on X-ray, mechanical and shrinkage investigations, some parameters of the structure of the non-crystalline regions are estimated. A structure model for the high-modulus polyethylene filaments is discussed.
    Notes: Die übermolekulare Struktur scherkristallisierter PE-Fäden unterschiedlicher Kristallisationstemperatur sowie getemperter und zonengereckter Proben wird mittels Röntgenbeugung charakterisiert. Erstmalig an derartigen Fäden werden die Gitterstörungen in den Kristalliten quantitativ angegeben. Die Ergebnisse zeigen, daß ein direkter Zusammenhang zwischen den Kristallitgrößen und dem Ausmaß der Gitterstörungen einerseits und dem axialen E-Modulandereseits ausgeschlossen werden kann. Auf Basis von Röntgen-, Modul- und Schrumpfmessungen werden Abschätzungen zum Aufbau der ungeordneten Bereiche durchgeführt und daraus Modellvorstellungen zur Struktur hochmoduliger PE-Fäden mitgeteilt.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 37 (1986), S. 557-563 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Blown films of LD-PE prepared with varying processing conditions have been investigated using different X-ray diffraction methods. All films have a-texture. Differences in the degree of orientation are noticed. Arragement and size of lamellae are estimated by SAXS-investigations. A WAXS peak separation procedure using Pearson-VII-functions allows the determination of crystallite sizes. The orthorhombic modification as the dominant crystalline phase and some amount of monoclinic modification of PE have been detected from the resolved WAXS pattern.
    Notes: Blasfolien aus LD-PE unterschiedlicher Herstellungsparameter wurden komplex röntgenographisch untersucht. Alle Folien bestizen eine a-Textur. Unterschiede in der Texturgüte werden angegeben. SAXS-Untersuchungen ermöglichen Aussagen zur Lamellenanordnung und -größe. Eine Peak-Separation der WAXS mittels Pearson-VII-Funktionen erlaubt Kristallitgrößenangaben und läßt monokline Anteile neben der hauptsächlich auftretenden orthorhombischen Modifikation erkennen.
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 1 (1989), S. 399-400 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 147-162 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The fusion welding behavior of a medium density polyethylene resin has been studied for a wide range of heating rates using a recently developed test methodology. With this method, the thermal and physical phenomena occurring at the interface of two thin polyethylene pieces assembled by fusion can be studied. It consists of a thermal welding phase and a phase of mechanical separation of the welded assembly. For the mechanical phase, an adaptation of the T-peel test was used. These conditions make it possible to determine the thermal welding parameters (temperature, time) for optimal mechanical quality of the joint, according to a criterion established by optimization of the peel test used. The variations in minimum temperature required for an optimum weld, as a function of heating rate, can be simulated with a numerical model based on the concept of macromolecular interdiffusion. Consistent with the experimental behavior, the numerical model involves two parameters characteristic of the diffusion behavior of the polyethylene resin. Thus, these parameters characterize the weldability of the polyethylene resin under study.
    Additional Material: 8 Ill.
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