ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The (MoVO)3+ -containing [Fe4S4]2+ agglomerate {(Ph4P)2[Fe4S4(tmbdt)2 (MoVO)0,76]}n (tmbdt = 2,4,6-trimethylbenzene-1,3-dithiolato) was synthesized by reaction of {(Ph4P)2[Fe4S4(tmbdt)2]}n and MoVOCl3(thf)2. The (MoVO)3+ cation is coordinated to the sulfur ligands binding the [Fe4S4]2+ core. The (MoVO)3+ -containing [Fe4S4]2+ agglomerate exhibits catalytic activity for the reduction of azobenzene and phenylacetylene to hydrazobenzene and phenylethylene, respectively, by Et4NBH4 in N,N-dimethylformamide/alcohol.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1990.021910807
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