ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of [Fe2(CO)9] with 2-exo,3-exo-bis(chloromethyl)-5,6-di(methylidene)-7-oxabicycio[2.2.1]-heptane (5) and with 5,6-di(methylidene)-7-oxabicyclo[2.2.1]heptane-2-exo,3-exo-dimethyl bis(methanesulfonate) (6) afforded, together with the corresponding [exo-Fe(CO)3(1,3-diene)] complexes 7 and 8, the products of dimerization in the form of stable [Fe(CO)2{(1,2,3-η:6,7,8-η)-octa-2,6-diene-1,8-diyl}] complexes 9 and 10, respectively, with high stereoselectivity. The structure of 10 was established by means of single-crystal X-ray diffraction.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19910740418
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