ISSN:
1572-879X
Keywords:
Oxidative coupling of methane
;
oxidative dehydrogenation of propane
;
ionic conductors
;
oxygen diffusivity
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The oxidative coupling of methane (OCM) and the oxidative dehydrogenation of propane (ODHP) have been performed on new mixed Bi-V oxides having a -γ-Bi2MoO6-like structure. The results yield a correlation between the methane conversion and the oxygen diffusivity. The introduction of metals (Fe, Cu, Sr with 10 mol%) improves the C2 selectivity. The use of an oxide with a scheelite structure (BiVO4) shows that, under catalytic conditions, this oxide has the same behaviour as the above solids.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00769161
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