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  • 1990-1994  (2,583)
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  • 1
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    Unknown
    East Melbourne : Department of Energy and Minerals Government of Victoria
    Call number: K 96.0075
    Pages: 1 Kt. + Erl.-H. (68 S.)
    Series Statement: Geological Survey of Victoria report 92
    Language: English
    Branch Library: GFZ Library
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  • 2
    Call number: SR 90.0001(1894)
    In: U.S. Geological Survey bulletin
    Type of Medium: Series available for loan
    Pages: VI, 36 S. + 3 pl.
    Series Statement: U.S. Geological Survey bulletin 1894
    Language: English
    Location: Lower compact magazine
    Branch Library: GFZ Library
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  • 3
    Unknown
    Basel, Boston, Berlin : Birkhäuser
    Keywords: fractals ; chaos ; geophysics ; geology
    Pages: Online-Ressource (VII, 180 Seiten)
    ISBN: 9783034863896
    Language: English
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  • 4
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 141 (1993), S. 111-124 
    ISSN: 1420-9136
    Keywords: Radon emanation ; soil air ; active faults ; fault creep ; fault gouge ; fractures ; permeability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Radon emanation is known to be anomalously high along active faults in many parts of the world. We tested this relationship in California during July and early August 1992, using a portable radonmeter to conduct soil-air radon surveys at 5 sites across three kinds of faults: Creeping, locked, and freshly broken. Along a 350-m long survey line across a creeping segment of the San Andreas fault at Nyland Ranch in San Juan Bautista, we found anomalous radon concentrations not in the creep zone itself as determined by a creepmeter, but on the adjacent sides, 10 and 30 meters from the center line of the fault. The anomalous values were 5 times higher than the background values measured farther away from the fault. A similar radon anomaly was observed along a 420-m long survey line across a creeping segment of the Calaveras fault near 7th Street in Hollister. There, the anomalous values were about 6 to 11 times the background values and about 40 and 50 m from the center line of the fault. The double-peaked featire of the anomalies may be indicative of a relatively low gas permeability of the fault-gouge materials in the creeping zones and high permeability of fractured rocks in the adjacent shear zones. Along a 144-m survey line across the currently locked segment of the San Andreas fault at the Earthquake Trail near Olema, the radon concentration was indeed anomalously high in the fault zone, by a factor of two above background values. However, the maximum values (3 to 6 times background) again were recorded about 10 meters from the center line. Three weeks after the magnitude 7.5 Landers earthquake of 28 June 1992, we conducted a survey along a 300-m line across the earthquake fault alongside Encantado Road in the epicenter area. The radon values measured at the two main fault breaks were an order of magnitude higher than the background values. A similar result was found along a 420-m line alongside Reche Road about 1.7 km south of Encantado Road.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 43 (1994), S. 1445-1450 
    ISSN: 1573-9171
    Keywords: metal carbonyls ; catalysis ; carbon monoxide ; formate ; water gas shift reaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The water gas shift reaction (CO + H2O = CO2+ H2) is catalyzed by aqueous metal carbonyl systems derived from simple mononuclear carbonyls such as Fe(CO)5 and M(CO)6 (M = Cr, Mo, and W) and bases in the 140–200 °C temperature range. The water gas shift reaction in a basic methanol-water solution containing Fe(CO)5 is first order in [Fe(CO)5], zero order in [CO], and essentially independent of base concentration and appears to involve an associative mechanism with a metallocarboxylate intermediate [(CO)4Fe-CO2H]−. The water gas shift reactions using M(CO)6 as catalyst precursors are first order in [M(CO)6], inverse first order in [CO], and first order in [HCO2 −] and appear to involve a dissociative mechanism with formatometallate intermediates [(CO)5M-OCHO]−. The Reppe hydroformylation of ethylene to produce propionaldehyde and 1-propanol in basic solutions containing Fe(CO)5 occurs at 110–140 °C. This reaction is second order in [Fe(CO)5], first order in [C2H4] up to a saturation pressure 〉1.5 MPa, and inhibited by [CO]. These experimental results suggest a mechanism where the rate-determining step involves a binuclear iron carbonyl intermediate. The substitution of Et3N for NaOH as the base facilitates the reduction of propionaldehyde to 1-propanol but results in a slower rate for the overall reaction. The homogeneous photocatalytic decomposition of the formate ion to H2 and CO2 in the presence of Cr(CO)6 appears to be closely related to the water gas shift reaction. The rate of H2 production from the formate ion exhibits saturation kinetics in the formate ion and is inhibited by added pyridine. The infrared spectra of the catalyst solutions indicate an LCr(CO)5 intermediate. Photolysis of the Cr(CO)6/formate system in aqueous methanol in the presence of an aldehyde RCHO (R =n-heptyl,p-tolyl, andp-anisyl) results in catalytic hydrogenation of the aldehyde to the corresponding alcohol RCH2OH by the formate ion. Detailed kinetic studies onp-tolualdehyde hydrogenation by this method indicates saturation kinetics in formate ion, autoinhibition by thep-tolualdehyde, and a threshold effect for Cr(CO)6 at concentrations 〉0.004 mol L−1. The presence of an aldehyde can interrupt the water gas shift catalytic cycle by interception of an HCr(CO)5 − intermediate by the aldehyde.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 38 (1990), S. 27-34 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The molecular transform is an alternate means of considering numerical representations of molecules in a manner designed to generate indices that can be related to structural and physiochemical parameters. The literature has shown that the transform, actually the Fourier transform, is operable on representations such as Cartesian coordinates or graphically derived depictious reflected by adjacency or distance matrices. The resulting curve may be used to give a binary index of the molecule or integrated to give an area-related index; either of these indices may be used as a correlation parameter in structure-activity studies. In this instance the individual bond distance matrices of a series of structurally diverse compounds served as input for a transform program. The derived index was then used to correlate both physical property and pharmacological activity indices for the series; correlation coefficients were comparable to those reported for the valence molecular connectivity parameter of Kier and Hall. The study also showed that lower correlation coefficients resulted when the index was based on the transform of hydrogen-suppressed structures.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The mechanical performance of advanced composite materials depends to a large extent on the adhesion between the fiber and matrix. This is especially true for maximizing the strength of unidirectional composites in off-axis directions. The materials of interest in this study were PAN-based carbon fibers (XA and A4) used in combination with a thermoset (EPON 828 epoxy) and a thermoplastic (liquid crystal poymer) matrix. The effect of surface treatment and sizing were evaluated by measuring the short-beam shear (SBS) and transverse flexural (TF) tensile strengths of unidirectional composites. Results indicated that fiber surface treatment improves the shear and trasverse tensile strengths for both thermosetting and thermoplastic matrix/carbon fiber-reinforced unidirectional composites. A small additional improvement in strengths was observed as the result of sizing treated fibers for the epoxy composites. Scanning electron microscope photomicrographs were used to determine the location of composite failure, relative to the fiber-matrix interface. Finally, the epoxy composites SBS and TF strengths appear to be limited to the maximum transeverse tensile strength of the epoxy matrix, while the thermoplastic composite SBS and TF strengths are limited by the LCP matrix shear and transverse tensile strengths, respectively.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 10
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