ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Irradiation of benzyldicarbonyl(η5-cyclopentadienyl)iron complex (2) leads to hemolytic cleavage of the Fe—C bond. In the presence of activated alkenes, radical addition occurs and both saturated and unsaturated addition products 7-9 are formed. Photolysis of alkyliron complexes 2,3 and 20 in the presence of acrylonitrile leads to the same products as the irradiation of the respective acyliron complexes 28-30. This indicates that, under photolytical conditions, alkyl and acyl complexes are in equilibrium with each other.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19910740524
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