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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 113 (1991), S. 9747-9756 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6977-6979 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic resonance spectra at 12–36 GHz are reported for Fe2+(3d6, S=2) in the 1D Ising ferromagnet [(CH3)3NH]FeCl3⋅2H2O, known as FeTAC, between 2.5 and 13 K. The main signal was identified as a spin-cluster resonance (SCR) because of its characteristic temperature dependence below 6 K and the linear dependence of the resonance field on the microwave frequency for H parallel to the easy axis at 4.2 K. The temperature dependence of the line intensity was fitted to the function exp[−(2J+hν)/kBT], with 2J/kB=(41±1) K, and the linear field dependence was explained by the value gz=8.26±0.05 in the S=1/2 representation and a demagnetization field of several hundred gauss, which depended on the sample shape. A frequency-dependent satellite structure observed on the low field side of the main line, which appeared as a broad line below 15 GHz, is tentatively associated with energy shifts of the lower-lying spin-cluster states produced by the magnetic dipole interaction and other terms in the Hamiltonian.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron paramagnetic resonance measurements at 36 GHz and in the range 12–18 GHz were made on a single crystal of the 1D Ising ferromagnet [(CH3)3 NH] FeCl3⋅2H2O, known as FeTAC, containing a nominal 10% of the isomorphous compound CoTAC. While the 4.2 K spectra obtained with the external field parallel to the chain axis were similar to the spin cluster resonance spectra previously identified in pure FeTAC, differences in the low-field satellite structure were observed, which are tentatively attributed to differences in the dipolar interaction and to shorter ferrous chains. An appreciable decrease in the strength of the demagnetizing field is associated with the tendency of the Co2+ moments to align perpendicularly to the chain axis.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have deposited diamond films with micron-size crystals on Si〈111〉 using low-pressure hot-filament-assisted chemical vapor deposition. These films have been characterized by positron annihilation, Raman spectroscopy, scanning electron microscopy, and x-ray photoelectron spectroscopy. In addition to the results for the electronic structure and morphology, we also present new results for the lattice defects present in these films.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Plant, cell & environment 15 (1992), S. 0 
    ISSN: 1365-3040
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: To eliminate the confusion in the definition of leaf area index (L) for non-flat leaves, the projection coefficients of several objects including spheres, cylinders, hemicircular cylinders, and triangular and square bars are investigated through mathematical derivation and numerical calculation for a range of ellipsoidal angular distributions. It is shown that the projection coefficient calculated based on half the total intercepting area is close to a constant of 0.5 when the inclination angle of the objects is randomly (spherically) distributed, whereas the calculated results based on the object's largest projected area are strongly dependent on the shape of the objects. Therefore, it is suggested that the leaf area index of non-flat leaves be defined as half the total intercepting area per unit ground surface area and that the definition of L based on the projected leaf area be abandoned.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Boundary layer meteorology 64 (1993), S. 149-174 
    ISSN: 1573-1472
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract This is the first of two papers reporting the results of a study of the turbulence regimes and exchange processes within and above an extensive Douglas-fir stand. The experiment was conducted on Vancouver Island during a two-week rainless period in July and August 1990. The experimental site was located on a 5o slope. The stand, which was planted in 1962, and thinned and pruned uniformly in 1988, had a (projected) leaf area index of 5.4 and a heighth=16.7 m. Two eddy correlation units were operated in the daytime to measure the fluctuations in the three velocity components, air temperature and water vapour density, with one mounted permanently at a height of 23.0m (z/h=1.38) and the other at various heights in the stand with two to three 8-hour periods of measurement at each level. Humidity and radiation regimes both above and beneath the overstory and profiles of wind speed and air temperature were also measured. The most important findings are: (1) A marked secondary maximum in the wind speed profile occurred in the middle of the trunk space (aroundz/h=0.12). The turbulence intensities for the longitudinal and lateral velocity components increased with decreasing height, but the intensity for the vertical velocity component had a maximum atz/h=0.60 (middle of the canopy layer). Magnitudes of the higher order moments (skewness and kurtosis) for the three velocity components were higher in the canopy layer than in the trunk space and above the stand. (2) There was a 20% reduction in Reynolds stress fromz/h=1.00 to 1.38. Negative Reynolds stress or upward momentum flux perisistently occurred atz/h=0.12 and 0.42 (base of the canopy), and was correlated with negative wind speed gradients at the two heights. The longitudinal pressure gradient due to the land-sea/upslope-downslope circulations was believed to be the main factor responsible for the negative Reynolds stress. (3) Momentum transfer was highly intermittent. Sweep and ejection events dominated the transfer atz/h=0.60, 1.00 and 1.38, with sweeps playing the more important role of the two atz/h=0.60 and 1.00 and the less important role atz/h=1.38. But interaction events were of greater magnitude than sweep and ejection events atz/h=0.12 and 0.42.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Boundary layer meteorology 64 (1993), S. 369-389 
    ISSN: 1573-1472
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract This is the second paper describing a study of the turbulence regimes and exchange processes within and above an extensive Douglas-fir stand. The experiment was conducted on Vancouver Island during a two-week rainless period in July and August 1990. Two eddy correlation units were operated in the daytime to measure the fluxes of sensible heat and water vapour and other turbulence statistics at various heights within and above the stand. Net radiation was measured above the overstory using a stationary net radiometer and beneath the overstory using a tram system. Supplementary measurements included soil heat flux, humidity above and beneath the overstory, profiles of wind speed and air temperature, and the spatial variation of sensible heat flux near the forest floor. The sum of sensible and latent heat fluxes above the stand accounted for, on average, 83% of the available energy flux. On some days, energy budget closure was far better than on others. The average value of the Bowen ratio was 2.1 above the stand and 1.4 beneath the overstory. The mid-morning value of the canopy resistance was 150–450 s/m during the experiment and mid-day value of the Omega factor was about 0.20. The daytime mean canopy resistance showed a strong dependence on the mean saturation deficit during the two-week experimental period. The sum of sensible and latent heat fluxes beneath the overstory accounted for 74% of the available energy flux beneath the overstory. One of the reasons for this energy imbalance was that the small number of soil heat flux plates and the short pathway of the radiometer tram system was unable to account for the large horizontal heterogeneity in the available energy flux beneath the overstory. On the other hand, good agreement was obtained among the measurements of sensible heat flux made near the forest floor at four positions 15 m apart. There was a constant flux layer in the trunk space, a large flux divergence in the canopy layer, and a constant flux layer above the stand. Counter-gradient flux of sensible heat constantly occurred at the base of the canopy. The transfer of sensible heat and water vapour was dominated by intermittent cool downdraft and warm updraft events and dry downdraft and moist updraft events, respectively, at all levels. For sensible heat flux, the ratio of the contribution of cool downdrafts to that of warm updrafts was greater than one in the canopy layer and less than one above the stand and near the forest floor.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1573-1472
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Comparison was made of the flux measurements of a closed-path CO2/H2O analyzer and an open-path H2O analyzer above a clover field and the forest floor of a Douglas-fir stand. The attenuation of the gas concentration fluctuations caused by the sampling tube of the closed-path analyzer resulted in underestimation of the H20 flux above both surfaces. The degree of underestimation above the clover field depended on wind speed, but was smaller than that calculated from the transfer function for laminar flow in a circular tube and the scalar cospectrum in the neutral and unstable surface layer. Above the forest floor CO2 fluctuations led those of H2O by ∼0.7s. The implications of this are discussed regarding the determination of the time delay caused by the sampling tube of the closedpath analyzer. The day-time CO2 efflux from the forest floor, averaged over three days, was 0.043 mg/(m2s).
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 22 (1990), S. 39-62 
    ISSN: 1573-8868
    Keywords: synthetic generation ; stochastic process ; random field ; heterogeneity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract The simulation of one-dimensional stationary correlated fields is of increasing importance in the earth sciences. A new method for repeated generation of independent realizations, which are long and dense relative to the correlation scale of the underlying stochastic process, is examined here. This method is conceptually simple and easy to apply. It consists of a matrix-factorization technique for derivation of moving average coefficients which are used as weights in the construction of successive observations from linear combinations of random normal deviates. The matrix-factorization procedure is fast and need be performed only once for a given correlation function and density of observations. This technique can be used to generate evenly spaced observations in time or a single space dimension for any prescribed correlation function and marginal distribution which is Gaussian with arbitrary mean and variance. Tests of ensemble properties of generation procedures have been developed and results for this method compared with those for a popular generation technique. For correlation functions and generation conditions examined, the matrix-factorization moving average approach more accurately produces ensemble characteristics of the prescribed underlying process. For repeated generation of 2001 observations spaced evenly over realizations with length equal to 100 times the correlation scale, the moving average approach requires only about one fifth the CPU time used by the Shinozuka and Jan method to obtain similar accuracy.
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  • 10
    Publication Date: 1991-07-01
    Description: Measurements of the spatial mean values of global irradiance, photosynthetic photon flux density, and the downward longwave irradiance under a 26-year-old, second-growth Douglas-fir (Pseudotsugamenziesii (Mirb.) Franco) forest canopy on a 26° south-facing slope were made with a tramway system, which scanned a 20-m transect in 12 min. The diffuse solar irradiance under the canopy was measured with a stationary pyranometer equipped with a shadow band. The extinction coefficients for the direct, global, and photon components were derived as functions of the solar incident angle over the range of 15° to 85°. The extinction coefficient for the diffuse radiation was found to correlate well with the ratio of the direct to diffuse irradiance above the canopy. Complete diurnal cycles of the downward longwave irradiance were simulated with a simple model based on the air temperature inside the stand. Analyses of the measurements of all the shortwave and longwave components were made using an effective leaf area index, which was derived from the measurements of the direct irradiance above and below the stand. It was found that the distribution of the leaf inclination angle of a Douglas-fir canopy has strong planophile characteristics, and that in the case of a forest stand on a slope, it is critical to obtain the characteristics of the light transmission through the canopy over the entire incident angle range before effective leaf area index is calculated. Warren Wilson's 57.5° approximation did not hold for the Douglas-fir canopy, which had distinct foliage clumping features.
    Print ISSN: 0045-5067
    Electronic ISSN: 1208-6037
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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